(a) Interpretation: The structural formula of 1 , 3 , 5 -trifluorobenzene is to be written. Concept introduction: The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule. In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used. The format to name the molecule that contains a benzene ring is as follows: substituent number-substitutent namebenzene The structure of benzene is as follows:

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Answer 1

Question

Chapter 21, Problem 21.5TC

Interpretation Introduction

(a)

Interpretation:

The structural formula of 1,3,5-trifluorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

Interpretation Introduction

(b)

Interpretation:

The structural formula of p-dichlorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. Halogens are represented by ‘halo’ prefix. For example: if chlorine is substituted in the hydrocarbon chain, ‘chloro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

When two hydrogen atoms are substituted from the benzene ring, the prefixes such as ortho (o), meta (m) and para (p) are used to indicate the position of substituents. Ortho indicates 1, 2 position, meta indicates 1, 3 position and para indicates 1, 4 position with respect to each other.

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Questions 4 and 5

For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.

Predict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.

Answer 2

Question

Chapter 21, Problem 21.5TC

Interpretation Introduction

(a)

Interpretation:

The structural formula of 1,3,5-trifluorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

Interpretation Introduction

(b)

Interpretation:

The structural formula of p-dichlorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. Halogens are represented by ‘halo’ prefix. For example: if chlorine is substituted in the hydrocarbon chain, ‘chloro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

When two hydrogen atoms are substituted from the benzene ring, the prefixes such as ortho (o), meta (m) and para (p) are used to indicate the position of substituents. Ortho indicates 1, 2 position, meta indicates 1, 3 position and para indicates 1, 4 position with respect to each other.

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Answer 3

Question

Chapter 21, Problem 21.5TC

Interpretation Introduction

(a)

Interpretation:

The structural formula of 1,3,5-trifluorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

Interpretation Introduction

(b)

Interpretation:

The structural formula of p-dichlorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. Halogens are represented by ‘halo’ prefix. For example: if chlorine is substituted in the hydrocarbon chain, ‘chloro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

When two hydrogen atoms are substituted from the benzene ring, the prefixes such as ortho (o), meta (m) and para (p) are used to indicate the position of substituents. Ortho indicates 1, 2 position, meta indicates 1, 3 position and para indicates 1, 4 position with respect to each other.

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Answer 4

Question

Chapter 21, Problem 21.5TC

Interpretation Introduction

(a)

Interpretation:

The structural formula of 1,3,5-trifluorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

Interpretation Introduction

(b)

Interpretation:

The structural formula of p-dichlorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. Halogens are represented by ‘halo’ prefix. For example: if chlorine is substituted in the hydrocarbon chain, ‘chloro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

When two hydrogen atoms are substituted from the benzene ring, the prefixes such as ortho (o), meta (m) and para (p) are used to indicate the position of substituents. Ortho indicates 1, 2 position, meta indicates 1, 3 position and para indicates 1, 4 position with respect to each other.

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Answer 5

Chapter 21, Problem 21.5TC

Interpretation Introduction

(a)

Interpretation:

The structural formula of 1,3,5-trifluorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

Interpretation Introduction

(b)

Interpretation:

The structural formula of p-dichlorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. Halogens are represented by ‘halo’ prefix. For example: if chlorine is substituted in the hydrocarbon chain, ‘chloro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

When two hydrogen atoms are substituted from the benzene ring, the prefixes such as ortho (o), meta (m) and para (p) are used to indicate the position of substituents. Ortho indicates 1, 2 position, meta indicates 1, 3 position and para indicates 1, 4 position with respect to each other.

Answer 6

Chapter 21, Problem 21.5TC

Interpretation Introduction

(a)

Interpretation:

The structural formula of 1,3,5-trifluorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

Answer 7

Chapter 21, Problem 21.5TC

Interpretation Introduction

(a)

Interpretation:

The structural formula of 1,3,5-trifluorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. The numbers before the Greek prefix represents the positions of the substituents. Halogens are represented by ‘halo’ prefix. For example: if fluorine is substituted in the hydrocarbon chain, ‘fluoro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structural formula of p-dichlorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. Halogens are represented by ‘halo’ prefix. For example: if chlorine is substituted in the hydrocarbon chain, ‘chloro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

When two hydrogen atoms are substituted from the benzene ring, the prefixes such as ortho (o), meta (m) and para (p) are used to indicate the position of substituents. Ortho indicates 1, 2 position, meta indicates 1, 3 position and para indicates 1, 4 position with respect to each other.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structural formula of p-dichlorobenzene is to be written.

Concept introduction:

The structural formula is a simplified model that represents the arrangement of atoms and bonds in a molecule.

In the IUPAC name of an organic compound, the Greek prefix indicates the number of the substituents present in the molecule. Halogens are represented by ‘halo’ prefix. For example: if chlorine is substituted in the hydrocarbon chain, ‘chloro’ prefix is used.

The format to name the molecule that contains a benzene ring is as follows:

substituent number-substitutent namebenzene

The structure of benzene is as follows:

When two hydrogen atoms are substituted from the benzene ring, the prefixes such as ortho (o), meta (m) and para (p) are used to indicate the position of substituents. Ortho indicates 1, 2 position, meta indicates 1, 3 position and para indicates 1, 4 position with respect to each other.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 1E Ch. 21 - Prob. 2E Ch. 21 - Prob. 3E Ch. 21 - Prob. 4E Ch. 21 - Prob. 5E Ch. 21 - Prob. 6E Ch. 21 - Prob. 7E Ch. 21 - Prob. 8E Ch. 21 - Prob. 9E Ch. 21 - Prob. 10E

Solution Summary: The structural formula of 1,3,5-trifluorobenzene is as follows: the Greek prefix indicates the number of the substituents present in the molecule.

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