Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
2nd Edition
ISBN: 9781337086431
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 21, Problem 38E
Interpretation Introduction
Interpretation: The structural isomers in Exercise 37 that exhibit cis-trans isomerism are to be stated.
Concept introduction: Structural isomerism occurs when two compounds have the same number of atoms, but the spatial arrangement of the atoms is different from each other. These isomers have the same formula, but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond, but in trans isomer, they are on the opposite side of the double bond.
To determine: The structural isomers in Exercise 37 that exhibit cis-trans isomerism.
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
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1200
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Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 21 Solutions
Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQCh. 21 - Prob. 8RQCh. 21 - Prob. 9RQCh. 21 - Prob. 10RQ
Ch. 21 - Prob. 11RQCh. 21 - Prob. 12RQCh. 21 - Prob. 1QCh. 21 - Prob. 2QCh. 21 - What is wrong with the following names? Give the...Ch. 21 - Prob. 4QCh. 21 - Prob. 5QCh. 21 - Prob. 6QCh. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 12QCh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Draw all the structural isomers for C8H18 that...Ch. 21 - Draw all the structural isomers for C8H18 that...Ch. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Draw the structural formula for each of the...Ch. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Name each of the following alkenes. a. CH2 = CH ...Ch. 21 - Name each of the following alkenes or alkynes. a....Ch. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 21 - Prob. 32ECh. 21 - There is only one compound that is named...Ch. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Draw all structural and geometrical (cistrans)...Ch. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - If one hydrogen in a hydrocarbon is replaced by a...Ch. 21 - There are three isomers of dichlorobenzene, one of...Ch. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Minoxidil (C9H15N5O) is a compound produced by...Ch. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Name all the alcohols that have the formula...Ch. 21 - Prob. 54ECh. 21 - Prob. 55ECh. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Complete the following reactions. a. CH3CO2H +...Ch. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - The polyester formed from lactic acid, is used for...Ch. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Prob. 89ECh. 21 - Prob. 90ECh. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Prob. 94ECh. 21 - Prob. 95ECh. 21 - Prob. 96ECh. 21 - Prob. 97ECh. 21 - Prob. 98ECh. 21 - Prob. 99ECh. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Which base will hydrogen-bond with uracil within...Ch. 21 - Prob. 108ECh. 21 - The base sequences in mRNA that code for certain...Ch. 21 - Prob. 110ECh. 21 - Prob. 111AECh. 21 - Prob. 112AECh. 21 - Prob. 113AECh. 21 - Prob. 114AECh. 21 - Prob. 115AECh. 21 - Prob. 116AECh. 21 - Prob. 117AECh. 21 - Prob. 118AECh. 21 - Prob. 119AECh. 21 - Prob. 120AECh. 21 - Prob. 121AECh. 21 - Prob. 122AECh. 21 - Prob. 123AECh. 21 - Prob. 124AECh. 21 - Prob. 125AECh. 21 - Prob. 126AECh. 21 - Prob. 127AECh. 21 - Prob. 128AECh. 21 - Prob. 129AECh. 21 - Prob. 130AECh. 21 - Prob. 131AECh. 21 - Prob. 132AECh. 21 - Prob. 133AECh. 21 - Prob. 134AECh. 21 - When heat is added to proteins, the hydrogen...Ch. 21 - Prob. 136AECh. 21 - Prob. 137CWPCh. 21 - Prob. 138CWPCh. 21 - Prob. 139CWPCh. 21 - Name each of the following alkenes and alkynes. a....Ch. 21 - a. Name each of the following alcohols. b. Name...Ch. 21 - Prob. 142CWPCh. 21 - Prob. 143CWPCh. 21 - Prob. 144CWPCh. 21 - Prob. 145CPCh. 21 - Prob. 146CPCh. 21 - Prob. 147CPCh. 21 - Prob. 148CPCh. 21 - Prob. 149CPCh. 21 - Prob. 150CPCh. 21 - Prob. 151CPCh. 21 - Prob. 152CPCh. 21 - Prob. 153CPCh. 21 - Prob. 154CPCh. 21 - Stretch a rubber band while holding it gently to...Ch. 21 - Alcohols are very useful starting materials for...Ch. 21 - Prob. 157CPCh. 21 - Prob. 158CPCh. 21 - Prob. 159IPCh. 21 - Prob. 160IPCh. 21 - Prob. 161MPCh. 21 - Prob. 162MP
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