The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms. Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon. To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

Question

Indicate the processes in the dismutation of Cu2O.

Answer 1

Question

Chapter 21, Problem 146CP

(a)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

(b)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The structure of the tetra peptide containing the synthetic amino acid.

(c)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The chiral carbon atoms present in the synthetic amino acid.

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Indicate the processes in the dismutation of Cu2O.

1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 Potential Energy (kJ) 600 400 200 0 -200- -400 -600- -800 (i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s) (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) Ea = 1550 kJ Ea = 2240 kJ (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2350 kJ AH=-950 kJ ΔΗ = 575 ΚΙ AH=-825 kJ a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ Reaction Progress b. What is the overall chemical equation? c. What is the overall change in enthalpy for the above chemical reaction? d. What is the overall amount of activation energy for the above chemical reaction? e. Which reaction intermediate would be considered a catalyst (if any) and why? f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would you be able to make the reaction reverse itself (i.e. have…

draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.

Answer 2

Question

Chapter 21, Problem 146CP

(a)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

(b)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The structure of the tetra peptide containing the synthetic amino acid.

(c)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The chiral carbon atoms present in the synthetic amino acid.

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Answer 3

Question

Chapter 21, Problem 146CP

(a)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

(b)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The structure of the tetra peptide containing the synthetic amino acid.

(c)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The chiral carbon atoms present in the synthetic amino acid.

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Answer 4

Question

Chapter 21, Problem 146CP

(a)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

(b)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The structure of the tetra peptide containing the synthetic amino acid.

(c)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The chiral carbon atoms present in the synthetic amino acid.

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Answer 5

Chapter 21, Problem 146CP

(a)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

(b)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The structure of the tetra peptide containing the synthetic amino acid.

(c)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The chiral carbon atoms present in the synthetic amino acid.

Answer 6

Chapter 21, Problem 146CP

(a)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

Answer 7

Chapter 21, Problem 146CP

(a)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The naturally occurring amino acid which is similar to the given non-naturally occurring amino acid.

Answer 8

(b)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The structure of the tetra peptide containing the synthetic amino acid.

Answer 9

(b)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The structure of the tetra peptide containing the synthetic amino acid.

Answer 10

(c)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The chiral carbon atoms present in the synthetic amino acid.

Answer 11

(c)

Interpretation Introduction

Interpretation: The naturally occurring amino acid to which the given amino acid is similar is to be named. The structure of the tetra peptide containing the synthetic amino acid is to be drawn indicating its chiral carbon atoms.

Concept introduction: When two or more amino acids are linked in a chain, a compound called peptide is formed in which the carboxyl group of each acid is joined to the amino group of the next forming a -OC-NH- bond, known as peptide bond. A tetra peptide is defined as an oligopeptide as it is formed by joining four amino acids by peptide linkage and a chiral carbon atom is one that is attached to four different types of atoms or groups of atoms and also known as asymmetric carbon.

To determine: The chiral carbon atoms present in the synthetic amino acid.

Answer 12

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Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains the structure of the tetra peptide containing the synthetic amino acid indicating its chiral carbon atoms.

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