The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis - trans isomerism are to be stated. Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis -isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond. To determine: The compounds that have same physical properties.

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Answer 1

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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Answer 2

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 3

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 4

Question

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 5

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 6

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

Answer 7

Chapter 21, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

Answer 8

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

Answer 9

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

Answer 10

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 11

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - What is a hydrocarbon? What is the difference...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Summarize the nomenclature rules for alkanes,...Ch. 21 - What functional group distinguishes each of the...Ch. 21 - Distinguish between isomerism and resonance....Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that structural isomerism occurs when two compounds have the same number of atoms but the spatial arrangement is different from each other.

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