The VSEPR formula of ClO 2 − has to be given. Concept Introduction: Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows: Steric number Number of lone pairs Molecular geometry Bond angles 2 0 Linear 180 ° 3 0 1 Trigonal planar Bent 120 ° 4 0 1 2 Tetrahedral Trigonal pyramidal Bent 109.5 ° 5 0 1 2 3 Trigonal Bi-pyramidal See-Saw T-shaped Linear 90 ° ,120 ° , 180 ° 6 0 1 2 Octahedral Square pyramidal Square planar 90 ° , 180 °

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Answer 1

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 2

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 4

Question

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 5

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 7

Chapter 2, Problem 2E.3BST

(b)

Interpretation Introduction

Interpretation:

The VSEPR formula of ClO2− has to be given.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 8

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 2 - Prob. 2A.1AST Ch. 2 - Prob. 2A.1BST Ch. 2 - Prob. 2A.2AST Ch. 2 - Prob. 2A.2BST Ch. 2 - Prob. 2A.3AST Ch. 2 - Prob. 2A.3BST Ch. 2 - Prob. 2A.4AST Ch. 2 - Prob. 2A.4BST Ch. 2 - Prob. 2A.1E Ch. 2 - Prob. 2A.2E

Solution Summary: The author explains that the Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion.

Concept explainers

Videos

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Want to see the full answer?

Chapter 2 Solutions

Solution Summary: The author explains that the Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion.

Concept explainers

Videos

Interpretation: The electron arrangement of ClO2− has to be predicted. Concept Introduction: Refer to part (a).

Interpretation: The shape of ClO2− has to be predicted. Concept Introduction: Refer to part (a).

Want to see the full answer?

Chapter 2 Solutions

Interpretation:

The electron arrangement of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).

Interpretation:

The shape of ClO2− has to be predicted.

Concept Introduction:

Refer to part (a).