The shape of ClO 2 − molecule has to be predicted. Concept Introduction: Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows: Number of electron pairs Molecular shape 2 Linear 3 Trigonal Planar 4 Tetrahedral 5 Trigonal Bipyramidal 6 Octahedral 7 Pentagonal Bipyramidal In order to determine the shape the steps to be followed are indicated as follows: 1. Lewis structure of molecule should be written. 2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms. 3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape. For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows: Steric number Number of lone pairs Molecular geometry Bond angles 2 0 Linear 180 ° 3 0 1 Trigonal planar Bent 120 ° 4 0 1 2 Tetrahedral Trigonal pyramidal Bent 109.5 ° 5 0 1 2 3 Trigonal Bi-pyramidal See-Saw T-shaped Linear 90 ° ,120 ° , 180 ° 6 0 1 2 Octahedral Square pyramidal Square planar 90 ° , 180 °

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Answer 1

Question

Chapter 2, Problem 2E.6E

(a)

Interpretation Introduction

Interpretation:

The shape of ClO2− molecule has to be predicted.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows:

Number ofelectron pairsMolecular shape2Linear3Trigonal Planar4Tetrahedral5Trigonal Bipyramidal6Octahedral7Pentagonal Bipyramidal

In order to determine the shape the steps to be followed are indicated as follows:

1. Lewis structure of molecule should be written.

2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms.

3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape.

For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

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Answer 2

Question

Chapter 2, Problem 2E.6E

(a)

Interpretation Introduction

Interpretation:

The shape of ClO2− molecule has to be predicted.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows:

Number ofelectron pairsMolecular shape2Linear3Trigonal Planar4Tetrahedral5Trigonal Bipyramidal6Octahedral7Pentagonal Bipyramidal

In order to determine the shape the steps to be followed are indicated as follows:

1. Lewis structure of molecule should be written.

2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms.

3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape.

For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 2, Problem 2E.6E

(a)

Interpretation Introduction

Interpretation:

The shape of ClO2− molecule has to be predicted.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows:

Number ofelectron pairsMolecular shape2Linear3Trigonal Planar4Tetrahedral5Trigonal Bipyramidal6Octahedral7Pentagonal Bipyramidal

In order to determine the shape the steps to be followed are indicated as follows:

1. Lewis structure of molecule should be written.

2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms.

3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape.

For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 4

Question

Chapter 2, Problem 2E.6E

(a)

Interpretation Introduction

Interpretation:

The shape of ClO2− molecule has to be predicted.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows:

Number ofelectron pairsMolecular shape2Linear3Trigonal Planar4Tetrahedral5Trigonal Bipyramidal6Octahedral7Pentagonal Bipyramidal

In order to determine the shape the steps to be followed are indicated as follows:

1. Lewis structure of molecule should be written.

2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms.

3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape.

For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 5

Chapter 2, Problem 2E.6E

(a)

Interpretation Introduction

Interpretation:

The shape of ClO2− molecule has to be predicted.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows:

Number ofelectron pairsMolecular shape2Linear3Trigonal Planar4Tetrahedral5Trigonal Bipyramidal6Octahedral7Pentagonal Bipyramidal

In order to determine the shape the steps to be followed are indicated as follows:

1. Lewis structure of molecule should be written.

2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms.

3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape.

For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

(b)

Interpretation Introduction

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 2, Problem 2E.6E

(a)

Interpretation Introduction

Interpretation:

The shape of ClO2− molecule has to be predicted.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows:

Number ofelectron pairsMolecular shape2Linear3Trigonal Planar4Tetrahedral5Trigonal Bipyramidal6Octahedral7Pentagonal Bipyramidal

In order to determine the shape the steps to be followed are indicated as follows:

1. Lewis structure of molecule should be written.

2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms.

3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape.

For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 7

Chapter 2, Problem 2E.6E

(a)

Interpretation Introduction

Interpretation:

The shape of ClO2− molecule has to be predicted.

Concept Introduction:

Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion. For the molecules that have no lone pairs around the central atom the bonded-atom unshared -pair arrangement is decided by the table as follows:

Number ofelectron pairsMolecular shape2Linear3Trigonal Planar4Tetrahedral5Trigonal Bipyramidal6Octahedral7Pentagonal Bipyramidal

In order to determine the shape the steps to be followed are indicated as follows:

1. Lewis structure of molecule should be written.

2. The type electron arrangement around the central atom should be identified around the central atom. This essentially refers to determination of bond pairs and unshared or lone pairs around central atoms.

3. Then bonded-atom unshared -pair arrangement that can maximize the distance of electron pairs about central atom determines the shape.

For molecules that have lone pairs around central atom, lone pairs influence shape, because there are no atoms at the positions occupied by these lone pairs. The key rule that governs the molecular shape, in this case, is the extent of lone –lone pair repulsions are far greater than lone bond pair or bond pair-bond pair repulsions. The table that summarized the molecular shapes possible for various combinations of bonded and lone pairs are given as follows:

Steric numberNumber of lone pairsMolecular geometryBond angles20Linear180 °301Trigonal planarBent120 °4012TetrahedralTrigonal pyramidalBent109.5 °50123Trigonal Bi-pyramidalSee-SawT-shapedLinear90 °,120 °,180 °6012OctahedralSquare pyramidalSquare planar90 °,180 °

Answer 8

(b)

Interpretation Introduction

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 2 - Prob. 2A.1AST Ch. 2 - Prob. 2A.1BST Ch. 2 - Prob. 2A.2AST Ch. 2 - Prob. 2A.2BST Ch. 2 - Prob. 2A.3AST Ch. 2 - Prob. 2A.3BST Ch. 2 - Prob. 2A.4AST Ch. 2 - Prob. 2A.4BST Ch. 2 - Prob. 2A.1E Ch. 2 - Prob. 2A.2E

Solution Summary: The author explains that the Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion.

Concept explainers

Videos

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).

Want to see the full answer?

Chapter 2 Solutions

Solution Summary: The author explains that the Valence Shell Electron Pair Repulsion model predicts shape by inclusion of bond angles and most distant arrangement of atoms that leads to minimum repulsion.

Concept explainers

Videos

Interpretation: The expected O−Cl−O bond angle of ClO2− molecule has to be predicted. Concept Introduction: Refer to part (a).

Want to see the full answer?

Chapter 2 Solutions

Interpretation:

The expected O−Cl−O bond angle of ClO2− molecule has to be predicted.

Concept Introduction:

Refer to part (a).