1 Fundamental Concepts Of Thermodynamics 2 Heat, Work, Internal Energy, Enthalpy, And The First Law Of Thermodynamics 3 The Importance Of State Functions: Internal Energy And Enthalpy 4 Thermochemistry 5 Entropy And The Second And Third Laws Of Thermodynamics 6 Chemical Equilibrium 7 The Properties Of Real Gases 8 Phase Diagrams And The Relative Stability Of Solids, Liquids, And Gases 9 Ideal And Real Solutions 10 Electrolyte Solutions 11 Electrochemical Cells, Batteries, And Fuel Cells 12 Probability 13 The Boltzmann Distribution 14 Ensemble And Molecular Partition Functions 15 Statistical Thermodynamics 16 Kinetic Theory Of Gases 17 Transport Phenomena 18 Elementary Chemical Kinetics 19 Complex Reaction Mechanisms expand_more
Chapter Questions expand_more
Problem 2.1CP: Electrical current is passed through a resistor immersed in a liquid in an adiabatic container. The... Problem 2.2CP: Two ideal gas systems undergo reversible expansion under different conditions starting from the same... Problem 2.3CP: You have a liquid and its gaseous form in equilibrium in a piston and cylinder assembly in a... Problem 2.4CP Problem 2.5CP: For a constant pressure process, H=qp. Does it follow that qp is a state function? Explain. Problem 2.6CP: A cup of water at 278 K (the system) is placed in a microwave oven and the oven is turned on for 1... Problem 2.7CP: In the experiments shown in Figure 2.4a and 2.4b, Usurrondings0, but Tsurrondings0. Explain how this... Problem 2.8CP: What is wrong with the following statement? Burns caused by steam at 100C can be more severe than... Problem 2.9CP: Why is it incorrect to speak of the heat or work associated with a system? Problem 2.10CP: You have a liquid and its gaseous form in equilibrium in a piston and cylinder assembly in a... Problem 2.11CP Problem 2.12CP: Explain how a mass of water in the surroundings can be used to determine q for a process. Calculate... Problem 2.13CP: A chemical reaction occurs in a constant volume enclosure separated from the surroundings by... Problem 2.14CP: Explain the relationship between the terms exact differential and state function. Problem 2.15CP: In the experiment shown in Figure 2.4b, the weight drops in a very short time. How will the... Problem 2.16CP: Discuss the following statement: If the temperature of the system increased, heat must have been... Problem 2.17CP: Discuss the following statement: Heating an object causes its temperature to increase. Problem 2.18CP: An ideal gas is expanded reversibly and adiabatically. Decide which of q, w, U, and H are positive,... Problem 2.19CP: An ideal gas is expanded reversibly and isothermally. Decide which of q, w, U, and H are positive,... Problem 2.20CP: An ideal gas is expanded adiabatically into a vacuum. Decide which of q, w, U, and H are positive,... Problem 2.21CP Problem 2.22CP Problem 2.23CP: A student gets up from her chair and pushes a stack of books across the table. They fall to the... Problem 2.24CP: Explain why ethene has a higher value for CV,m at 800 K than CO. Problem 2.25CP Problem 2.26CP Problem 2.1NP: A 3.75 mole sample of an ideal gas with Cv,m=3R/2 initially at a temperature Ti=298K and Pi=1.00 bar... Problem 2.2NP: The temperature of 1.75 moles of an ideal gas increases from 10.2C to 48.6C as the gas is compressed... Problem 2.3NP: A 2.50 mole sample of an ideal gas, for which Cv,m=3R/2, is subjected to two successive changes in... Problem 2.4NP: A hiker caught in a thunderstorm loses heat when her clothing becomes wet. She is packing emergency... Problem 2.5NP: Count Rumford observed that using cannon boring machinery a single horse could heat 11.6 kg of ice... Problem 2.6NP: A 1.50 mole sample of an ideal gas at 28.5C expands isothermally from an initial volume of 22.5dm3... Problem 2.7NP: Calculate q, w, U, and H if 2.25 mol of an ideal gas with Cv,m=3R/2 undergoes a reversible adiabatic... Problem 2.8NP: Calculate w for the adiabatic expansion of 2.50 mol of an ideal gas at an initial pressure of 2.25... Problem 2.9NP Problem 2.10NP: A muscle fiber contracts by 3.5 cm and in doing so lifts a weight. Calculate the work performed by... Problem 2.11NP: A cylindrical vessel with rigid adiabatic walls is separated into two parts by a frictionless... Problem 2.12NP: In the reversible adiabatic expansion of 1.75 mol of an ideal gas from an initial temperature of... Problem 2.13NP: A system consisting of 82.5 g of liquid water at 300. K is heated using an immersion heater at a... Problem 2.14NP: A 1.25 mole sample of an ideal gas is expanded from 320. K and an initial pressure of 3.10 bar to a... Problem 2.15NP: A bottle at 325 K contains an ideal gas at a pressure of 162.5103Pa. The rubber stopper closing the... Problem 2.16NP: A 2.25 mole sample of an ideal gas with Cv,m=3R/2 initially at 310. K and 1.25105Pa undergoes a... Problem 2.17NP Problem 2.18NP: An ideal gas undergoes an expansion from the initial state described by Pi,Vi, T to a final state... Problem 2.19NP: An ideal gas described by Ti=275K,Pi=1.10bar, and Vi=10.0L is heated at constant volume until... Problem 2.20NP: In an adiabatic compression of one mole of an ideal gas with Cv,m=5R/2, the temperature rises from... Problem 2.21NP: The heat capacity of solid lead oxide is given by CP,m=44.35+1.47103TKinunitsofJK1mol1 Calculate the... Problem 2.22NP Problem 2.23NP Problem 2.24NP Problem 2.25NP Problem 2.26NP: A 2.50 mol sample of an ideal gas for which Cv,m=3R/2 undergoes the following two-step process: (1)... Problem 2.27NP: A 2.35 mole sample of an ideal gas, for which Cv,m=3R/2, initially at 27.0C and 1.75106Pa, undergoes... Problem 2.28NP Problem 2.29NP: A nearly flat bicycle tire becomes noticeably warmer after it has been pumped up. Approximate this... Problem 2.30NP Problem 2.31NP Problem 2.32NP: Consider the isothermal expansion of 2.35 mol of an ideal gas at 415 K from an initial pressure of... Problem 2.33NP: An automobile tire contains air at 225103Pa at 25.0C. The stem valve is removed and the air is... Problem 2.34NP: One mole of an ideal gas is subjected to the following changes. Calculate the change in temperature... Problem 2.35NP Problem 2.36NP: A pellet of Zn of mass 31.2 g is dropped into a flask containing dilute H2SO4 at a pressure of... Problem 2.37NP: Calculate H and U for the transformation of 2.50 mol of an ideal gas from 19.0C and 1.00 atm to... Problem 2.38NP: A 1.75 mole sample of an ideal gas for which CV,m=20.8JK1mol1 is heated from an initial temperature... Problem 2.39NP Problem 2.40NP Problem 2.41NP: The Youngs modulus (see Problem P2.40) of muscle fiber is approximately 2.80107Pa. A muscle fiber... Problem 2.42NP: DNA can be modeled as an elastic rod that can be twisted or bent. Suppose a DNA molecule of length L... Problem 2.43NP Problem 2.44NP format_list_bulleted