A bottle at 325 K contains an ideal gas at a pressure of
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Thermodynamics, Statistical Thermodynamics, & Kinetics
- Which of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forwardFor the reaction BaCO3(s) BaO(s) + CO2(g), rG = +219.7 kJ/mol-rxn. Using this value and other data available in Appendix L, calculate the value of fG for BaCO3(s).arrow_forwardUse the two appropriate values of R to determine a conversion between L. atm and J.arrow_forward
- What are the two ways that a final chemical state of a system can be more probable than its initial state?arrow_forwardBenzoic acid, C6H5COOH, is a common standard used in bomb calorimeters, which maintain a constant volume. If 1.20 g of benzoic acid gives off 31, 723 J of energy when burned in the presence of excess oxygen and in a water bath having a temperature of 24.6 C, calculate q, w, H, and U for the reaction.arrow_forwardUse the data in Table 2.2 to determine Hp T for Ar at 0C and 1atm. Make any reasonable assumptions necessary.arrow_forward
- Consider 2.00 moles of an ideal gas that are taken from state A (PA = 2.00 atm, vA = 10.0 L) to state B (PB = 1.00 attn, VB = 30.0 L) by two different pathways: These pathways are summarized on the following graph of P versus V: Calculate the work (in units of J) associated with the two pathways. Is work a state function? Explain.arrow_forwardCalculate the work for the isothermal, reversible compressionof 0.245 moleof an idealgas going from 1.000L to 1.00 mL if the temperature were 95.0C.arrow_forwardWhy is equation2.37 written interms of CV and Cp and not c-v and c-p ?arrow_forward
- We are all familiar with the general principles of operation of an internal combustion reaction: the combustion of fuel drives out the piston. It is possible to imagine engines that use reactions other than combustions, and we need to assess the work they can do. A chemical reaction takes place in a container of cross-sectional area 100 cm2; the container has a piston at one end. As a result of the reaction, the piston is pushed out through 10.0 cm against a constant external pressure of 100 kPa. Calculate the work done by the system.arrow_forward5. One mole of a monatomic ideal gas is compressed adiabatically in a single stage with a constant opposing pressure equal to 10 atm. Initially the gas is at 27 °C and 1 atm pressure, the final pressure is 10 atm. How would the various quantities be affected if n moles were used instead of one mole? For a monatomic ideal gas. C₂ = Cv R. 2arrow_forwardQ1arrow_forward
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