Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 19.1, Problem 19.2QC
Interpretation Introduction
Interpretation: The Fischer projections of all 2-ketopentose need to be drawn along with their descriptions as D-2-ketopentoses, L-2-ketopentoses and enantiomers.
Concept Introduction: A convention used to represent a 3-D stereoformula in 2-D representation is said to be Fischer projections. In this projection, the vertical lines represent bonds below the plane of the paper and horizontal lines represents bonds above the plane of the paper.
For a D-sugar, the
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Identify the type of glycosidic bond in the following disaccharide.
CH,OH
H
H
ОН Н
CH2
H
H
H
ОН Н
HO
ОН
H.
ОН
HO
H
H
OH
O B-1,4-glycosidic bond
O a-1,4-glycosidic bond
O B-1,6-glycosidic bond
O a-1,6-glycosidic bond
O deoxy carboxylic acid pentose
O carboxylic acid pentose
O aldopentose
Question 6
Classify the following monosaccharide.
C-H
H NH2
Но
H
-OH-
ČH,OH
O aminohexose
O ketotetrose
O deoxyhexose
O aldohexose
O carboxylic acid heptose
Question 7
Classify the following monosaccharide.
CH.OH
MacBook Pro
Draw Fischer projections for all 2-ketopentoses. Which are d-2-ketopentoses, which are l-2-ketopentoses, and which are enantiomers?
Chapter 19 Solutions
Introduction to General, Organic and Biochemistry
Ch. 19.1 - Prob. 19.1QCCh. 19.1 - Prob. 19.2QCCh. 19.2 - Prob. 19.3QCCh. 19.3 - Prob. 19.4QCCh. 19.4 - Prob. 19.5QCCh. 19.5 - Prob. 19.6QCCh. 19 - Prob. 1PCh. 19 - Prob. 2PCh. 19 - Prob. 3PCh. 19 - Prob. 4P
Ch. 19 - Prob. 5PCh. 19 - Prob. 6PCh. 19 - Prob. 7PCh. 19 - Prob. 8PCh. 19 - Prob. 9PCh. 19 - Prob. 10PCh. 19 - Prob. 11PCh. 19 - Prob. 12PCh. 19 - Prob. 13PCh. 19 - Prob. 14PCh. 19 - Prob. 15PCh. 19 - Prob. 16PCh. 19 - Prob. 17PCh. 19 - Prob. 18PCh. 19 - Prob. 19PCh. 19 - Prob. 20PCh. 19 - Prob. 21PCh. 19 - Prob. 22PCh. 19 - Prob. 23PCh. 19 - Prob. 24PCh. 19 - Prob. 25PCh. 19 - Prob. 26PCh. 19 - Prob. 27PCh. 19 - Prob. 28PCh. 19 - Prob. 29PCh. 19 - Prob. 30PCh. 19 - Prob. 31PCh. 19 - Prob. 32PCh. 19 - Prob. 33PCh. 19 - Prob. 34PCh. 19 - Prob. 35PCh. 19 - Prob. 36PCh. 19 - Prob. 37PCh. 19 - Prob. 38PCh. 19 - Prob. 39PCh. 19 - Prob. 40PCh. 19 - Prob. 41PCh. 19 - 6 Where is glycogen stored in the human body?Ch. 19 - Prob. 43PCh. 19 - 8 How is it possible that cows can digest grass...Ch. 19 - 1 Hyaluronic acid acts as a lubricant in the...Ch. 19 - Prob. 46PCh. 19 - Prob. 47PCh. 19 - Prob. 48PCh. 19 - Prob. 49PCh. 19 - Prob. 50PCh. 19 - Prob. 51PCh. 19 - Prob. 52PCh. 19 - Prob. 53PCh. 19 - Prob. 54PCh. 19 - Prob. 55PCh. 19 - Prob. 56PCh. 19 - Prob. 57PCh. 19 - Prob. 58PCh. 19 - Prob. 59PCh. 19 - Prob. 60PCh. 19 - Prob. 61PCh. 19 - Prob. 62PCh. 19 - Prob. 63PCh. 19 - Prob. 64PCh. 19 - Prob. 65PCh. 19 - Prob. 66PCh. 19 - Prob. 67PCh. 19 - Prob. 68PCh. 19 - Prob. 69PCh. 19 - Prob. 70PCh. 19 - Prob. 71PCh. 19 - Prob. 72PCh. 19 - Prob. 73PCh. 19 - Prob. 74PCh. 19 - Prob. 75P
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- Describe each glycosidic bond in this trisaccharide.arrow_forwardDisaccharides Disaccharides are carbohydrates composed of two monosaccharide units that are joined by a carbon-oxygen-carbon linkage known as a glycosidic linkage. Circle the disaccharide linkage in each of these disaccharides below. OH glucose OH HO HO OH HO HO HO но OH HO- HO OH OHO- HO OH HO glucose OH OH glucose OH OH OH glucose galactose -OH OH fructose maltose lactose sucrose There are different types of glycosidic linkages. They are characterized by the numbering of the alcohols that are linked in the ether. And the anomer of the sugar. For the maltose shown here, the sugars are [a/ẞ] anomers. Circle one. • Which alcohols are linked? Numbering proceeds around the ring starting with the anomeric carbon. OH HO HO HO 6 4 5 OH OHO- glucose 3 OH OH glucose Thus, this is alpha-1,4-maltose. Draw ẞ-1,4-maltose, where the glucose on the right has isomerized. 3 5 60arrow_forward2. Sucrose is a disaccharide formed from the condensation of glucose and fructose sugars. Draw the structure of sucrose that results from the condensation reaction between the indicated -OH groups. CH2OH 1, CH,OH он 1. OH но CH,OH OH HO H он OHarrow_forward
- Following is the Haworth structure of a disaccharide. Identify the type of glycosidic bond in this disaccharide. CH₂OH H HO H OH H H OH H H a-1,6-glycosidic bond O a,B-1,2-glycosidic bond O B-1,4-glycosidic bond O a-1,4-glycosidic bond CH₂OH H OH H H OH H OH B a hparrow_forwardClassify each monosaccharide according to the position of the carbonyl group and the number of carbon atoms in the molecule. CHO CH₂OH OH H -OH CH,OH aldotriose aldotetrose aldopentose ketotetrose ketotriose ketopentose galactose ketopentose aldotetrose ketotetrose ketohexose aldohexose aldopentose OH OH aldotetrose aldopentose ketohexose aldohexose ketopentose ketotetrosearrow_forwardClick the "draw structure" button to launch the drawing utility. Convert the cyclic form to an acyclic monosaccharide. CH₂OH O- H H OH HO H H OH draw structure 1b)Use a simple model to convert the following Fischer projection to a line structure showing stereochemistry Br OHC CH3 HO–|CH,CH3 H S d ww b Harrow_forward
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