Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 19, Problem 57P
Interpretation Introduction
Interpretation:
The difference in the glycosidic bonds in starch and cellulose and difference in their biological functions should be explained.
Concept introduction:
Starch is a mixture of amylopectin and amylose. It has a branch of d-glucose which is linked by the alpha-1,6 glycosidic bonds.
Glycogen is a branched chain of d-glucose which is linked by the alpha-1,6 glycosidic bonds.
Cellulose is a linear chain of D-glucose which is linked by the beta-1,4 glycosidic bonds.
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The product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1
and 2 below, in any arrangement you like.
1+2
NaBH3CN
H+
N
Click and drag to start drawing a
structure.
5
Assign this HSQC Spectrum ( please editing clearly on the image)
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
Chapter 19 Solutions
Introduction to General, Organic and Biochemistry
Ch. 19.1 - Prob. 19.1QCCh. 19.1 - Prob. 19.2QCCh. 19.2 - Prob. 19.3QCCh. 19.3 - Prob. 19.4QCCh. 19.4 - Prob. 19.5QCCh. 19.5 - Prob. 19.6QCCh. 19 - Prob. 1PCh. 19 - Prob. 2PCh. 19 - Prob. 3PCh. 19 - Prob. 4P
Ch. 19 - Prob. 5PCh. 19 - Prob. 6PCh. 19 - Prob. 7PCh. 19 - Prob. 8PCh. 19 - Prob. 9PCh. 19 - Prob. 10PCh. 19 - Prob. 11PCh. 19 - Prob. 12PCh. 19 - Prob. 13PCh. 19 - Prob. 14PCh. 19 - Prob. 15PCh. 19 - Prob. 16PCh. 19 - Prob. 17PCh. 19 - Prob. 18PCh. 19 - Prob. 19PCh. 19 - Prob. 20PCh. 19 - Prob. 21PCh. 19 - Prob. 22PCh. 19 - Prob. 23PCh. 19 - Prob. 24PCh. 19 - Prob. 25PCh. 19 - Prob. 26PCh. 19 - Prob. 27PCh. 19 - Prob. 28PCh. 19 - Prob. 29PCh. 19 - Prob. 30PCh. 19 - Prob. 31PCh. 19 - Prob. 32PCh. 19 - Prob. 33PCh. 19 - Prob. 34PCh. 19 - Prob. 35PCh. 19 - Prob. 36PCh. 19 - Prob. 37PCh. 19 - Prob. 38PCh. 19 - Prob. 39PCh. 19 - Prob. 40PCh. 19 - Prob. 41PCh. 19 - 6 Where is glycogen stored in the human body?Ch. 19 - Prob. 43PCh. 19 - 8 How is it possible that cows can digest grass...Ch. 19 - 1 Hyaluronic acid acts as a lubricant in the...Ch. 19 - Prob. 46PCh. 19 - Prob. 47PCh. 19 - Prob. 48PCh. 19 - Prob. 49PCh. 19 - Prob. 50PCh. 19 - Prob. 51PCh. 19 - Prob. 52PCh. 19 - Prob. 53PCh. 19 - Prob. 54PCh. 19 - Prob. 55PCh. 19 - Prob. 56PCh. 19 - Prob. 57PCh. 19 - Prob. 58PCh. 19 - Prob. 59PCh. 19 - Prob. 60PCh. 19 - Prob. 61PCh. 19 - Prob. 62PCh. 19 - Prob. 63PCh. 19 - Prob. 64PCh. 19 - Prob. 65PCh. 19 - Prob. 66PCh. 19 - Prob. 67PCh. 19 - Prob. 68PCh. 19 - Prob. 69PCh. 19 - Prob. 70PCh. 19 - Prob. 71PCh. 19 - Prob. 72PCh. 19 - Prob. 73PCh. 19 - Prob. 74PCh. 19 - Prob. 75P
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- Predict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forwardWhat would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forward
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