The building blocks which represents the sphingosine residues in the given block diagram of sphingoglycolipid have to be predicted. Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
The building blocks which represents the sphingosine residues in the given block diagram of sphingoglycolipid have to be predicted. Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
Solution Summary: The author explains that the building blocks which represent the sphingosine residues in the given block diagram, are A, B, and C.
Interpretation: The building blocks which represents the sphingosine residues in the given block diagram of sphingoglycolipid have to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
(b)
Interpretation Introduction
Interpretation: The building blocks which represents the mono- or oligosaccharide residues in the given block diagram of sphingoglycolipid have to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
(c)
Interpretation Introduction
Interpretation: The linkage which represents the glycosidic linkage in the given block diagram of sphingoglycolipid has to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
(d)
Interpretation Introduction
Interpretation: The linkages which involve both sphingosine and fatty acid residues in the given block diagram of sphingoglycolipid have to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
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