Concept explainers
(a)
Interpretation: Among the terms acidic hydrolysis, saponification, hydrogenation and oxidation, the term that can be applied to the given reaction change has to be predicted.
Concept introduction: The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.
The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
The process of converting a fat or oil into the fatty acid salts and glycerol in the presence of water and a base like
(b)
Interpretation: Among the terms acidic hydrolysis, saponification, hydrogenation and oxidation, the term that can be applied to the given reaction change has to be predicted.
Concept introduction: The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.
The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
The process of converting a fat or oil into the fatty acid salts and glycerol in the presence of water and a base like
(c)
Interpretation: Among the terms acidic hydrolysis, saponification, hydrogenation and oxidation, the term that can be applied to the given reaction change has to be predicted.
Concept introduction: The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.
The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
The process of converting a fat or oil into the fatty acid salts and glycerol in the presence of water and a base like
(d)
Interpretation: Among the terms acidic hydrolysis, saponification, hydrogenation and oxidation, the term that can be applied to the given reaction change has to be predicted.
Concept introduction: The hydrolysis of triacylglycerol is carried out in the presence of an acid or a base. The hydrolysis of triacylglycerol takes place in the presence of an acid forms glycerol and fatty acid as the desired products. The hydrolysis of triacylglycerol takes place in the presence of a base forms glycerol and fatty acid salts as the desired products.
The process of addition of hydrogen atoms across the carbon-carbon double or triple bond is known as hydrogenation. Hydrogenation is the process of converting an unsaturated compound into a saturated compound.
The process of converting a fat or oil into the fatty acid salts and glycerol in the presence of water and a base like

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Chapter 19 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium boratearrow_forwardUsing the table of Reactants and Products provided provide the correct letter that corresponds with the Carboxylic acid that is formed in the reaction below. 6 M NaOH Acid-workup WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES A) Pool of Reagents for Part B CI B) OH C) E) CI J) racemic F) K) OH N) OH P) G) OH D) HO H) L) M) HO Q) R) CI Aarrow_forwardIn the table below, the exact chemical structures for Methyl salicylate can be represented by the letter WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES CI B) A) E) Cl racemic F) J) CI K) N) OH P) Pool of Reagents for Part B OH OH G) L) OH D) HO H) M) HO Q) R) CIarrow_forward
- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
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