General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 19, Problem 19.68P
Interpretation Introduction
Interpretation:
The reason for the solubility of LDL in blood should be explained.
Concept Introduction:
Solute solubility in a solvent depends on various factors such as polarity of the solute, the molecular size of the solute. These factors are characteristics of the solute which is going to dissolve in a solvent. Temperature, pressure and the mechanical forces like stirring also affect the solubility of the solute in the solvent.
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1. Consider the following molecular-level diagrams of a titration.
O-HA molecule
-Aion
°°
о
°
(a)
о
(b)
(c)
(d)
a. Which diagram best illustrates the microscopic representation for the
EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium.
hydroxide?
(e)
Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single
file upload below:
Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
Chapter 19 Solutions
General, Organic, & Biological Chemistry
Ch. 19.1 - Prob. 19.1PCh. 19.1 - Prob. 19.2PCh. 19.2 - Prob. 19.3PCh. 19.2 - Prob. 19.4PCh. 19.2 - Prob. 19.5PCh. 19.3 - Prob. 19.6PCh. 19.3 - Prob. 19.7PCh. 19.3 - Prob. 19.8PCh. 19.3 - Prob. 19.9PCh. 19.4 - Prob. 19.10P
Ch. 19.4 - Prob. 19.11PCh. 19.4 - Prob. 19.12PCh. 19.4 - Prob. 19.13PCh. 19.5 - Review Section 5.2 on balancing chemical...Ch. 19.5 - Prob. 19.15PCh. 19.6 - Prob. 19.16PCh. 19.6 - Prob. 19.17PCh. 19.7 - Prob. 19.18PCh. 19.7 - Prob. 19.19PCh. 19.7 - Prob. 19.20PCh. 19.8 - Prob. 19.21PCh. 19.8 - Prob. 19.22PCh. 19.8 - Identify the functional groups in (a)...Ch. 19.9 - Compare the structures of estrone and...Ch. 19.9 - Prob. 19.25PCh. 19.10 - Prob. 19.26PCh. 19.11 - Prob. 19.27PCh. 19.11 - Prob. 19.28PCh. 19 - Label each compound as a hydrolyzable or...Ch. 19 - Label each compound as a hydrolyzable or...Ch. 19 - Prob. 19.31PCh. 19 - In which solvents or solutions might a steroid be...Ch. 19 - Prob. 19.33PCh. 19 - Prob. 19.34PCh. 19 - Prob. 19.35PCh. 19 - Prob. 19.36PCh. 19 - Some fish oils contain triacylglycerols formed...Ch. 19 - Some marine plankton contain triacylglycerols...Ch. 19 - Prob. 19.39PCh. 19 - Prob. 19.40PCh. 19 - Prob. 19.41PCh. 19 - Prob. 19.42PCh. 19 - What hydrolysis products are formed when each wax...Ch. 19 - What hydrolysis products are formed when each wax...Ch. 19 - Prob. 19.45PCh. 19 - Prob. 19.46PCh. 19 - Prob. 19.47PCh. 19 - Prob. 19.48PCh. 19 - Prob. 19.49PCh. 19 - Prob. 19.50PCh. 19 - Consider the following four types of compounds:...Ch. 19 - Prob. 19.52PCh. 19 - Answer the following questions about the given...Ch. 19 - Prob. 19.54PCh. 19 - Prob. 19.55PCh. 19 - Prob. 19.56PCh. 19 - Prob. 19.57PCh. 19 - Prob. 19.58PCh. 19 - Prob. 19.59PCh. 19 - Prob. 19.60PCh. 19 - Draw a phospholipid that fits each description. a...Ch. 19 - Draw a phospholipid that fits each description. a...Ch. 19 - Prob. 19.63PCh. 19 - Prob. 19.64PCh. 19 - Prob. 19.65PCh. 19 - Prob. 19.66PCh. 19 - Why must cholesterol be transported through the...Ch. 19 - Prob. 19.68PCh. 19 - Describe the role of HDLs and LDLs in cholesterol...Ch. 19 - Prob. 19.70PCh. 19 - (a) Draw the structure of an estrogen and an...Ch. 19 - Prob. 19.72PCh. 19 - What are the similarities and differences between...Ch. 19 - Prob. 19.74PCh. 19 - Prob. 19.75PCh. 19 - List three biological functions of prostaglandins...Ch. 19 - Explain why aspirin and celecoxib differ in how...Ch. 19 - How does zileuton treat the cause of asthma, not...Ch. 19 - Answer each question with regards to vitamins A...Ch. 19 - Answer each question in Problem 19.79 for vitamins...Ch. 19 - Prob. 19.81PCh. 19 - Prob. 19.82PCh. 19 - Prob. 19.83PCh. 19 - Prob. 19.84PCh. 19 - Prob. 19.85PCh. 19 - Prob. 19.86PCh. 19 - Prob. 19.87PCh. 19 - Prob. 19.88PCh. 19 - The main fatty acid component of the...Ch. 19 - Prob. 19.90PCh. 19 - Prob. 19.91PCh. 19 - Prob. 19.92PCh. 19 - Can an individual survive on a completely fat-free...Ch. 19 - Prob. 19.94PCh. 19 - Prob. 19.95PCh. 19 - Prob. 19.96PCh. 19 - Prob. 19.97PCh. 19 - Prob. 19.98PCh. 19 - Prob. 19.99CPCh. 19 - Prob. 19.100CP
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