General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 19, Problem 19.78P
How does zileuton treat the cause of asthma, not just relieve its symptoms?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 19 Solutions
General, Organic, & Biological Chemistry
Ch. 19.1 - Prob. 19.1PCh. 19.1 - Prob. 19.2PCh. 19.2 - Prob. 19.3PCh. 19.2 - Prob. 19.4PCh. 19.2 - Prob. 19.5PCh. 19.3 - Prob. 19.6PCh. 19.3 - Prob. 19.7PCh. 19.3 - Prob. 19.8PCh. 19.3 - Prob. 19.9PCh. 19.4 - Prob. 19.10P
Ch. 19.4 - Prob. 19.11PCh. 19.4 - Prob. 19.12PCh. 19.4 - Prob. 19.13PCh. 19.5 - Review Section 5.2 on balancing chemical...Ch. 19.5 - Prob. 19.15PCh. 19.6 - Prob. 19.16PCh. 19.6 - Prob. 19.17PCh. 19.7 - Prob. 19.18PCh. 19.7 - Prob. 19.19PCh. 19.7 - Prob. 19.20PCh. 19.8 - Prob. 19.21PCh. 19.8 - Prob. 19.22PCh. 19.8 - Identify the functional groups in (a)...Ch. 19.9 - Compare the structures of estrone and...Ch. 19.9 - Prob. 19.25PCh. 19.10 - Prob. 19.26PCh. 19.11 - Prob. 19.27PCh. 19.11 - Prob. 19.28PCh. 19 - Label each compound as a hydrolyzable or...Ch. 19 - Label each compound as a hydrolyzable or...Ch. 19 - Prob. 19.31PCh. 19 - In which solvents or solutions might a steroid be...Ch. 19 - Prob. 19.33PCh. 19 - Prob. 19.34PCh. 19 - Prob. 19.35PCh. 19 - Prob. 19.36PCh. 19 - Some fish oils contain triacylglycerols formed...Ch. 19 - Some marine plankton contain triacylglycerols...Ch. 19 - Prob. 19.39PCh. 19 - Prob. 19.40PCh. 19 - Prob. 19.41PCh. 19 - Prob. 19.42PCh. 19 - What hydrolysis products are formed when each wax...Ch. 19 - What hydrolysis products are formed when each wax...Ch. 19 - Prob. 19.45PCh. 19 - Prob. 19.46PCh. 19 - Prob. 19.47PCh. 19 - Prob. 19.48PCh. 19 - Prob. 19.49PCh. 19 - Prob. 19.50PCh. 19 - Consider the following four types of compounds:...Ch. 19 - Prob. 19.52PCh. 19 - Answer the following questions about the given...Ch. 19 - Prob. 19.54PCh. 19 - Prob. 19.55PCh. 19 - Prob. 19.56PCh. 19 - Prob. 19.57PCh. 19 - Prob. 19.58PCh. 19 - Prob. 19.59PCh. 19 - Prob. 19.60PCh. 19 - Draw a phospholipid that fits each description. a...Ch. 19 - Draw a phospholipid that fits each description. a...Ch. 19 - Prob. 19.63PCh. 19 - Prob. 19.64PCh. 19 - Prob. 19.65PCh. 19 - Prob. 19.66PCh. 19 - Why must cholesterol be transported through the...Ch. 19 - Prob. 19.68PCh. 19 - Describe the role of HDLs and LDLs in cholesterol...Ch. 19 - Prob. 19.70PCh. 19 - (a) Draw the structure of an estrogen and an...Ch. 19 - Prob. 19.72PCh. 19 - What are the similarities and differences between...Ch. 19 - Prob. 19.74PCh. 19 - Prob. 19.75PCh. 19 - List three biological functions of prostaglandins...Ch. 19 - Explain why aspirin and celecoxib differ in how...Ch. 19 - How does zileuton treat the cause of asthma, not...Ch. 19 - Answer each question with regards to vitamins A...Ch. 19 - Answer each question in Problem 19.79 for vitamins...Ch. 19 - Prob. 19.81PCh. 19 - Prob. 19.82PCh. 19 - Prob. 19.83PCh. 19 - Prob. 19.84PCh. 19 - Prob. 19.85PCh. 19 - Prob. 19.86PCh. 19 - Prob. 19.87PCh. 19 - Prob. 19.88PCh. 19 - The main fatty acid component of the...Ch. 19 - Prob. 19.90PCh. 19 - Prob. 19.91PCh. 19 - Prob. 19.92PCh. 19 - Can an individual survive on a completely fat-free...Ch. 19 - Prob. 19.94PCh. 19 - Prob. 19.95PCh. 19 - Prob. 19.96PCh. 19 - Prob. 19.97PCh. 19 - Prob. 19.98PCh. 19 - Prob. 19.99CPCh. 19 - Prob. 19.100CP
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- in the scope of the SCH4U course! please show all steps as im still learning how to format my answers in the format given, thank you!arrow_forwardhelp me solve this HWarrow_forwardMolecules of the form AH2 can exist in two potential geometries: linear or bent. Construct molecular orbital diagrams for linear and bent CH2. Identify the relevant point group, include all of the appropriate symmetry labels and pictures, and fill in the electrons. Which geometry would you predict to be more stable, and why? (Please draw out the diagram and explain)arrow_forward
- Indicate the variation in conductivity with concentration in solutions of strong electrolytes and weak electrolytes.arrow_forwardThe molar conductivity of a very dilute solution of NaCl has been determined. If it is diluted to one-fourth of the initial concentration, qualitatively explain how the molar conductivity of the new solution will compare with the first.arrow_forwardWhat does the phrase mean, if instead of 1 Faraday of electricity, Q coulombs (Q/F Faradays) pass through?arrow_forward
- What characteristics should an interface that forms an electrode have?arrow_forwardFor a weak acid AcH, calculate the dissociated fraction (alpha), if its concentration is 1.540 mol L-1 and the concentration [H+] is 5.01x10-4 mol L-1.arrow_forwardIf the molar conductivity at infinite dilution of HAC is A0 = 390.5 S cm² mol¹. Calculate the Arrhenius conductivity of a 9.3% by weight solution of HAc with a pH of 3.3. Data: molecular weight of HAC is 60.05 g/mol and the density of the solution is 1 g/cm³.arrow_forward
- If the molar conductivity at infinite dilution of HAC is A0 = 390.5 S cm² mol¹. Calculate the Arrhenius conductivity of a 9.3% by weight solution of HAc with a pH of 3.3. Data: molecular weight of HAC is 60.05 g/mol and the density of the solution is 1 g/cm³.arrow_forwardIf the molar conductivity at infinite dilution of HAC is A0 = 390.5 S cm² mol¹. Calculate the Arrhenius conductivity of a 9.3% by weight solution of HAc with a pH of 3.3. Data: molecular weight of HAC is 60.05 g/mol and the density of the solution is 1 g/cm³.arrow_forwardDetermine the distance between the metal and the OHP layer using the Helm- holtz model when the electrode's differential capacitance is 145 μF cm². DATA: dielectric constant of the medium for the interfacial zone &r= lectric constant of the vacuum &0 = 8.85-10-12 F m-1 = 50, die-arrow_forward
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