ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 1.9, Problem 1.22E

(a)

Interpretation Introduction

Interpretation:Thedashed-wedged line formulas for the isomers of C4H10 needs to be determined.

Concept Introduction:Constitutional isomers are the isomers with same molecular formula but different arrangement of bonded atoms in the molecule. Since they have same molecular formula but different bonding of atoms therefore they exhibit different properties. There are different ways to represent the structural formula such as line formula, wedge formula, condense formula etc.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 1.9, Problem 1.22E

(b)

Interpretation Introduction

Interpretation:Thebond line notation for the structure of benzylpenicillin, cubane and saccharine needs to be drawn.

Concept Introduction: Constitutional isomers are the isomers with same molecular formula but different arrangement of bonded atoms in the molecule. Since they have same molecular formula but different bonding of atoms therefore they exhibit different properties. There are different ways to represent the structural formula such as line formula, wedge formula, condense formula etc.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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