The hashed and wedged formulas should be converted to condensed form. Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds. Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

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Answer 1

Question

Chapter 1, Problem 42P

(a)

Interpretation Introduction

Interpretation:The hashed and wedged formulas should be converted to condensed form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 1, Problem 42P

(a)

Interpretation Introduction

Interpretation:The hashed and wedged formulas should be converted to condensed form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

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Answer 3

Question

Chapter 1, Problem 42P

(a)

Interpretation Introduction

Interpretation:The hashed and wedged formulas should be converted to condensed form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

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Answer 4

Question

Chapter 1, Problem 42P

(a)

Interpretation Introduction

Interpretation:The hashed and wedged formulas should be converted to condensed form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

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Answer 5

Chapter 1, Problem 42P

(a)

Interpretation Introduction

Interpretation:The hashed and wedged formulas should be converted to condensed form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(b)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

(c)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 6

Chapter 1, Problem 42P

(a)

Interpretation Introduction

Interpretation:The hashed and wedged formulas should be converted to condensed form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 7

Chapter 1, Problem 42P

(a)

Interpretation Introduction

Interpretation:The hashed and wedged formulas should be converted to condensed form.

Concept introduction:There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 8

(b)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 9

(b)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 10

(c)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 11

(c)

Interpretation Introduction

Interpretation: The hashed and wedged formulas should be converted to condensed form.

Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge.The bonds in plane are represented by normal bonds.

Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl while the non-terminal is for methylene group. For instance, the propane is written in this notation as follows:

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 1.3 - Prob. 1.1E Ch. 1.3 - Prob. 1.2E Ch. 1.3 - Prob. 1.3E Ch. 1.3 - Prob. 1.4E Ch. 1.3 - Prob. 1.5E Ch. 1.4 - Prob. 1.6E Ch. 1.4 - Prob. 1.8TIY Ch. 1.5 - Prob. 1.9E Ch. 1.5 - Prob. 1.11TIY Ch. 1.6 - Prob. 1.12E

Solution Summary: The author explains that the hashed and wedged formulas should be converted to condensed form.

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