ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 1.8, Problem 1.16E

(a)

Interpretation Introduction

Interpretation:Thehybridization and bonding in methyl cation CH3+ and methyl anion CH3- needs to be explained.

Concept Introduction:Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons.

To draw the Lewis structure, calculate the total number of valence electrons in each atom and draw the structure in such a way that each atom gets its octet configuration. From the Lewis structure, hybridization can be checked with the help of given formula:

  Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.

(b)

Interpretation Introduction

Interpretation:Theorbitals involved in CH3BH2 molecule needs to be determined.

Concept Introduction: Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons.

To draw the Lewis structure, calculate the total number of valence electrons in each atom and draw the structure in such a way that each atom gets its octet configuration. From the Lewis structure, hybridization can be checked with the help of given formula:

  Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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