Themolecular orbital for the bonding between atoms in H 2 and H 2 + needs to be drawn. Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types: Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital. Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital. Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital. Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

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Answer 1

Question

Chapter 1, Problem 35P

(a)

Interpretation Introduction

Interpretation:Themolecular orbital for the bonding between atoms in H2 and H2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(b)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in He2 and He2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(c)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in O2 and O2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(d)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in N2 and N2+ needs to be determined.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Answer 2

Question

Chapter 1, Problem 35P

(a)

Interpretation Introduction

Interpretation:Themolecular orbital for the bonding between atoms in H2 and H2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(b)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in He2 and He2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(c)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in O2 and O2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(d)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in N2 and N2+ needs to be determined.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 1, Problem 35P

(a)

Interpretation Introduction

Interpretation:Themolecular orbital for the bonding between atoms in H2 and H2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(b)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in He2 and He2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(c)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in O2 and O2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(d)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in N2 and N2+ needs to be determined.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 1, Problem 35P

(a)

Interpretation Introduction

Interpretation:Themolecular orbital for the bonding between atoms in H2 and H2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(b)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in He2 and He2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(c)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in O2 and O2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(d)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in N2 and N2+ needs to be determined.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 1, Problem 35P

(a)

Interpretation Introduction

Interpretation:Themolecular orbital for the bonding between atoms in H2 and H2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(b)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in He2 and He2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(c)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in O2 and O2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

(d)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in N2 and N2+ needs to be determined.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 6

Chapter 1, Problem 35P

(a)

Interpretation Introduction

Interpretation:Themolecular orbital for the bonding between atoms in H2 and H2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 7

Chapter 1, Problem 35P

(a)

Interpretation Introduction

Interpretation:Themolecular orbital for the bonding between atoms in H2 and H2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 8

(b)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in He2 and He2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 9

(b)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in He2 and He2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. Based on energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 10

(c)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in O2 and O2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 11

(c)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in O2 and O2+ needs to be drawn.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 12

(d)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in N2 and N2+ needs to be determined.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 13

(d)

Interpretation Introduction

Interpretation:The molecular orbital for the bonding between atoms in N2 and N2+ needs to be determined.

Concept Introduction: Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.

Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.

Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represent the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 1.3 - Prob. 1.1E Ch. 1.3 - Prob. 1.2E Ch. 1.3 - Prob. 1.3E Ch. 1.3 - Prob. 1.4E Ch. 1.3 - Prob. 1.5E Ch. 1.4 - Prob. 1.6E Ch. 1.4 - Prob. 1.8TIY Ch. 1.5 - Prob. 1.9E Ch. 1.5 - Prob. 1.11TIY Ch. 1.6 - Prob. 1.12E

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