ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 1, Problem 57P
Interpretation Introduction

Interpretation:The structure with bond angle closest to 120 ° should be chosen.

Concept introduction:In accordance with VSEPR model, if four bonds are present around the central atom then hybridization associated is sp3 and theses four orbitals tend to stay as far as 109.5 ° from one another so as to have minimum repulsions.

Similarly, if three bonds are present around the central atom then hybridization associated is sp2 and theses orbitals tend to stay as far as 120 ° from one another so as to have minimum repulsions.

The table that relates the hybridization with bond angles is as follows:

  Type of HybridisationBond anglesp180 ° sp2120 ° sp3109.5 ° sp3d90 °,120 °,180 ° sp3d290 °,180 °

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Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY