A complete and detailed mechanism for 1 , 3 − dithiane formation reaction is to be drawn. Concept introduction: If an aldehyde or ketone is treated with a large excess of an alcohol under acidic conditions, then the hemiacetal produced from nucleophilic addition reacts further to form an acetal, in which two alkoxy ( RO ) groups are bonded to the same carbon. The complete mechanism for this acetal formation reaction is shown in Equation 18-13: The sulfur analog of an acetal is produced when a ketone or aldehyde is treated with a thiol ( RSH ) under acidic conditions. This is called as thioacetal. When propane − 1 , 3 − dithiol is used, 1 , 3 − dithiane is produced. The mechanism is the same as that of equation 18-13. The only difference is that the coordination step 6 is intramolecular rather than intermolecular.

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.9P

Interpretation Introduction

Interpretation:

A complete and detailed mechanism for 1,3−dithiane formation reaction is to be drawn.

Concept introduction:

If an aldehyde or ketone is treated with a large excess of an alcohol under acidic conditions, then the hemiacetal produced from nucleophilic addition reacts further to form an acetal, in which two alkoxy (RO) groups are bonded to the same carbon. The complete mechanism for this acetal formation reaction is shown in Equation 18-13:

The sulfur analog of an acetal is produced when a ketone or aldehyde is treated with a thiol (RSH) under acidic conditions. This is called as thioacetal. When propane−1,3−dithiol is used, 1,3−dithiane is produced. The mechanism is the same as that of equation 18-13. The only difference is that the coordination step 6 is intramolecular rather than intermolecular.

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PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS FOR THE MECHANISM!!! THANKS First image: QUESTION 6. I have to show, with ARROWS and STRUCTURES, the mechanism of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary. I also tried to draw the mechanism, tell me what to change. Please note that its an AMIDE thats formed not an AMINE the nitrogen has ONE hydrogen and one Phenyl-C-Phenyl. I already asked for this mechanism and got as a final product ...-NH2 not whats shown on the picture, thank you Ths second part. QUESTION 3. I just need a way to synthesize the lactone A, I already started please continue from where I left it Second image: I simply need the products, substrates or reagents, thank you

Indicate how to prepare a 10% sodium hydroxide (NaOH) solution to a slightly alkaline pH.

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.9P

Interpretation Introduction

Interpretation:

A complete and detailed mechanism for 1,3−dithiane formation reaction is to be drawn.

Concept introduction:

If an aldehyde or ketone is treated with a large excess of an alcohol under acidic conditions, then the hemiacetal produced from nucleophilic addition reacts further to form an acetal, in which two alkoxy (RO) groups are bonded to the same carbon. The complete mechanism for this acetal formation reaction is shown in Equation 18-13:

The sulfur analog of an acetal is produced when a ketone or aldehyde is treated with a thiol (RSH) under acidic conditions. This is called as thioacetal. When propane−1,3−dithiol is used, 1,3−dithiane is produced. The mechanism is the same as that of equation 18-13. The only difference is that the coordination step 6 is intramolecular rather than intermolecular.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.9P

Interpretation Introduction

Interpretation:

A complete and detailed mechanism for 1,3−dithiane formation reaction is to be drawn.

Concept introduction:

If an aldehyde or ketone is treated with a large excess of an alcohol under acidic conditions, then the hemiacetal produced from nucleophilic addition reacts further to form an acetal, in which two alkoxy (RO) groups are bonded to the same carbon. The complete mechanism for this acetal formation reaction is shown in Equation 18-13:

The sulfur analog of an acetal is produced when a ketone or aldehyde is treated with a thiol (RSH) under acidic conditions. This is called as thioacetal. When propane−1,3−dithiol is used, 1,3−dithiane is produced. The mechanism is the same as that of equation 18-13. The only difference is that the coordination step 6 is intramolecular rather than intermolecular.

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.9P

Interpretation Introduction