(a) Interpretation: The product for given reaction is to be drawn. Concept introduction: Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

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Answer 1

Question

Chapter 18, Problem 18.9P

Interpretation Introduction

(a)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(b)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(c)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(d)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

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Draw a stepwise mechanism for the attached reaction sequence.

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Answer 2

Question

Chapter 18, Problem 18.9P

Interpretation Introduction

(a)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(b)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(c)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(d)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

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Answer 3

Question

Chapter 18, Problem 18.9P

Interpretation Introduction

(a)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(b)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(c)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(d)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

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Answer 4

Question

Chapter 18, Problem 18.9P

Interpretation Introduction

(a)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(b)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(c)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(d)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

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Answer 5

Chapter 18, Problem 18.9P

Interpretation Introduction

(a)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(b)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(c)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Interpretation Introduction

(d)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 6

Chapter 18, Problem 18.9P

Interpretation Introduction

(a)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 7

Chapter 18, Problem 18.9P

Interpretation Introduction

(a)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The product for given reaction is to be drawn.

Concept introduction:

Protonation of an alkene forms a carbocation. This carbocation acts as an electrophile in a Friedel-Craft alkylation. Protonation of an alcohol followed by loss of water forms a carbocation. Carbocation reacts with benzene to form a product of electrophilic aromatic substitution.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - What acid chloride would be needed to prepare each...Ch. 18 - Prob. 18.7P Ch. 18 - Draw a stepwise mechanism for the following...Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author explains that the product for given reaction is cyclohexyl benzene. Protonation of an alkene forms a carbocation.

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Chapter 18 Solutions