
(a)
Interpretation:
The complete, detailed mechanism and the major organic product for the given reaction is to be drawn.
Concept introduction:
When an

Answer to Problem 18.65P
The complete, detailed mechanism and the major organic product for the given reaction are shown below:
Explanation of Solution
The given reaction is as shown below:
The given reaction is aldol condensation as the sodium hydroxide and heat is given. Firstly, the given aldehyde is treated with sodium hydroxide to produce
The complete, detailed mechanism and the major organic product for the given reaction are shown below:
The complete, detailed mechanism and the major organic product for the given reaction are drawn by aldol addition reaction, followed by E1cb mechanism.
(b)
Interpretation:
The complete, detailed mechanism and the major organic product for the given reaction are to be drawn.
Concept introduction:
When an aldehyde is treated with sodium hydroxide, the product

Answer to Problem 18.65P
The complete, detailed mechanism and the major organic product for the given reaction are as shown below:
Explanation of Solution
The given reaction is shown below:
The given reaction is aldol condensation as the sodium hydroxide and heat is given. Firstly, the given aldehyde is treated with sodium hydroxide to produce
The complete, detailed mechanism and the major organic product for the given reaction are shown below:
The complete, detailed mechanism and the major organic product for the given reaction are drawn by aldol addition reaction followed by E1cb mechanism.
(c)
Interpretation:
The complete, detailed mechanism and the major organic product for the given reaction is to be drawn.
Concept introduction:
When an aldehyde is treated with sodium hydroxide, the product

Answer to Problem 18.65P
The complete, detailed mechanism and the major organic product for the given reaction are as shown below:
Explanation of Solution
The given reaction is shown below:
The given reaction is aldol addition as the sodium hydroxide is given. The given aldehyde is treated with sodium hydroxide to produce
The complete, detailed mechanism and the major organic product for the given reaction are shown below:
The complete, detailed mechanism and the major organic product for the given reaction are drawn by intramolecular aldol addition reaction mechanism.
(d)
Interpretation:
The complete, detailed mechanism and the major organic product for the given reaction are to be drawn.
Concept introduction:
When aldehyde is treated with sodium hydroxide, the product

Answer to Problem 18.65P
The complete, detailed mechanism and the major organic product for the given reaction are as shown below:
Explanation of Solution
The given reaction is shown below:
The given reaction is aldol condensation as the sodium hydroxide and heat is given. Firstly, the given aldehyde is treated with sodium hydroxide, to produce
The complete, detailed mechanism and the major organic product for given reaction are shown below:
The complete, detailed mechanism and the major organic product for given reaction are drawn on the basis of aldol addition reaction mechanism.
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Chapter 18 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
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