Concept explainers
(a)
Interpretation: The number of acetal and hemiacetal carbon atoms in the given disaccharide has to be predicted.
Concept introduction: If an
(b)
Interpretation: The number of acetal and hemiacetal carbon atoms in the given disaccharide has to be predicted.
Concept introduction: If an
(c)
Interpretation: The number of acetal and hemiacetal carbon atoms in the given disaccharide has to be predicted.
Concept introduction: If an
(d)
Interpretation: The number of acetal and hemiacetal carbon atoms in the given disaccharide has to be predicted.
Concept introduction: If an
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Chapter 18 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Identify the component monosaccharides of each of the following compounds and describe the type of glycosidic linkage in each.arrow_forwardConsider each of the following disaccharides: a) Label the acetal and hemiacetal in each disaccharide. b) Number the carbons in each of their monosaccharide rings. c) Classify the glycosidic linkage as α or β and use numbers to designate its location. d) Draw the Fishcher projections of the monosaccharides formed when each of thedisaccharides is hydrolyzed? e) Draw the chair conformation of each monosaccharide, where applicable.arrow_forwardModify the mannose structures provided to show the structure of a disaccharide formed from two mannose units joined by a 1 → 6-B-glycosidic linkage. CH₂OH Снон H ОН H Он Н H Он он OH Он Он H он Н H H H H Х Garrow_forward
- Consider the following statements: (1) The term sugar is a general designation for both monosaccharides and disaccharides. (2) The "penultimate carbon" in a monosaccharide is used to determine D- or L-configuration. (3) Sucrose is a reducing sugar and lactose is a nonreducing sugar. O Two of the three statements are true. All three statements are true. O Only one of the statements is true. None of the statements are true.arrow_forward1) Please list all glycosidic linkages between each monosaccharide units. For example, α(1→4)2) Please discuss whether these oligo/polysaccharides would be reducing or non-reducing sugar. Remember to state your reasoning in complete sentence.arrow_forwardName the three digestible disaccharides we talked about. What monosaccharides are they each made of and tell whether they are connected by an alpha 1-4 glycosidic linkage, a 1-4 beta glycosidic linkage or a 1-5 beta glycosidic linkage.arrow_forward
- Consider the disaccharide melibiose. CH,OH ОН Н H ОН H H CH2 Н ОН Н H ОН H ОН ОН H Н Он melibiose What monosaccharides are formed when melibiose is hydrolyzed? Modify the structure of the disaccharide to identify the two monosaccharide products. Снон Он H H Он H Н CH2 H ОН Н Н ОН Н Он ОН H H ОН Х :arrow_forwardIdentify the type of glycosidic linkage present in the disaccharide below: O a (16) O a (1-4) 08(1 - 6) 03(1-4) Н HO ОН OH OH O. H Н Н ОН H OH Н OH ОНarrow_forwardConsider the disaccharide melibiose. сон ОН H Он Н Н Н CH2 H Он H Н Он -= 5. о H H он H Он melibiose What monosaccharides are formed when melibiose is hydrolyzed? Modify the structure of the disaccharide to identify the two monosaccharide products. CH₂OH OH H H он Н H CH2 H Он Н Н Он H Он он Н Н Он х Ш:arrow_forward
- Which of the following monosaccharides structural relationship is CORRECT? * CHO CHO CHO но- H- HO -- но -H- но -OH- H- но -- H- H- H- OH но- -H- ČH2OH ČH,OH CH,OH 1 3 1 and 2 are enantiomers, while 2 and 3 are diastereomers 1 and 2 are diastereomers, while 2 and 3 are diastereomers 1 and 2 are enantiomers, while 2 and 3 are enantiomers O 1 and 2 are diastereomers, while 2 and 3 are enantiomersarrow_forwardA disaccharide that is found in dairy products can be formed by the two monosaccharides. Please draw the Haworth structure of this disaccharide and give the name of the glycosidic bond.arrow_forwardIdentify the monosaccharides and their linkages in the following disaccharide. HOCH, Но H. -0-CH2 OH Он Н н но ČH2OH H OH Но Harrow_forward
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