EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
7th Edition
ISBN: 9780100853188
Author: STOKER
Publisher: YUZU
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Chapter 18.20, Problem 1QQ
Interpretation Introduction
Interpretation: The type of compounds which are glycoproteins has to be identified.
Concept introduction: The carbohydrate-protein molecules are known as glycoproteins. A protein molecule which contain one or more carbohydrate or carbohydrate derivative units covalently attached to it is known as a glycoprotein.
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and
gives compound A.
?
NH2
Br
Br
Propose a structural formula for compound A.
You do not have to explicitly draw H atoms.
You do not have to consider stereochemistry.
In cases where there is more than one answer, just draw one.
R3N
C14H19NO2
+ 2 R3NH*Br
A
Chapter 18 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
Ch. 18.1 - In terms of mass percent, which of the following...Ch. 18.1 - Which of the following is the most abundant type...Ch. 18.2 - Which of the following statements concerning the...Ch. 18.2 - Prob. 2QQCh. 18.3 - Prob. 1QQCh. 18.3 - Prob. 2QQCh. 18.3 - Which of the following is not a possible value for...Ch. 18.3 - The complete hydrolysis of a polysaccharide...Ch. 18.4 - Prob. 1QQCh. 18.4 - Prob. 2QQ
Ch. 18.4 - Prob. 3QQCh. 18.4 - Prob. 4QQCh. 18.5 - Prob. 1QQCh. 18.5 - Prob. 2QQCh. 18.6 - Prob. 1QQCh. 18.6 - Which of the following Fischer projection formulas...Ch. 18.6 - Prob. 3QQCh. 18.6 - Prob. 4QQCh. 18.7 - Prob. 1QQCh. 18.7 - Prob. 2QQCh. 18.8 - Prob. 1QQCh. 18.8 - Which of the following statements about...Ch. 18.8 - The smallest monosaccharides that can exist are a....Ch. 18.9 - Prob. 1QQCh. 18.9 - Prob. 2QQCh. 18.9 - Prob. 3QQCh. 18.9 - In which of the following pairs of monosaccharides...Ch. 18.9 - In which of the following pairs of monosaccharides...Ch. 18.10 - Prob. 1QQCh. 18.10 - Which of the following structures represents a...Ch. 18.10 - Prob. 3QQCh. 18.10 - Prob. 4QQCh. 18.10 - Prob. 5QQCh. 18.11 - Prob. 1QQCh. 18.11 - Which of the following is the correct Haworth...Ch. 18.12 - Prob. 1QQCh. 18.12 - Prob. 2QQCh. 18.12 - Prob. 3QQCh. 18.12 - Prob. 4QQCh. 18.12 - Prob. 5QQCh. 18.13 - Which of the following disaccharides contains...Ch. 18.13 - Which of the following disaccharides will produce...Ch. 18.13 - In which of the following disaccharides is the...Ch. 18.13 - In which of the following pairs of disaccharides...Ch. 18.13 - Which of the following disaccharides is not a...Ch. 18.13 - The terms milk sugar and table sugar apply,...Ch. 18.14 - Prob. 1QQCh. 18.14 - Prob. 2QQCh. 18.15 - Which of the following statements about...Ch. 18.15 - Prob. 2QQCh. 18.16 - Prob. 1QQCh. 18.16 - Which of the following storage polysaccharides is...Ch. 18.16 - Prob. 3QQCh. 18.16 - Which of the following statements about storage...Ch. 18.17 - Prob. 1QQCh. 18.17 - Which of the following statements about cellulose...Ch. 18.17 - Chitin is a polysaccharide in which the...Ch. 18.18 - Which of the following statements about the...Ch. 18.18 - Prob. 2QQCh. 18.19 - Which of the following is not classified as a...Ch. 18.19 - Prob. 2QQCh. 18.20 - Prob. 1QQCh. 18.20 - Which of the following is not a biochemical...Ch. 18 - Prob. 18.1EPCh. 18 - Prob. 18.2EPCh. 18 - Prob. 18.3EPCh. 18 - Prob. 18.4EPCh. 18 - Prob. 18.5EPCh. 18 - Prob. 18.6EPCh. 18 - Prob. 18.7EPCh. 18 - Prob. 18.8EPCh. 18 - Prob. 18.9EPCh. 18 - Prob. 18.10EPCh. 18 - Prob. 18.11EPCh. 18 - Prob. 18.12EPCh. 18 - Prob. 18.13EPCh. 18 - Prob. 18.14EPCh. 18 - Prob. 18.15EPCh. 18 - Prob. 18.16EPCh. 18 - Prob. 18.17EPCh. 18 - Prob. 18.18EPCh. 18 - Prob. 18.19EPCh. 18 - Prob. 18.20EPCh. 18 - Prob. 18.21EPCh. 18 - Prob. 18.22EPCh. 18 - Prob. 18.23EPCh. 18 - Prob. 18.24EPCh. 18 - Prob. 18.25EPCh. 18 - Prob. 18.26EPCh. 18 - Prob. 18.27EPCh. 18 - Prob. 18.28EPCh. 18 - Prob. 18.29EPCh. 18 - Prob. 18.30EPCh. 18 - Prob. 18.31EPCh. 18 - Prob. 18.32EPCh. 18 - Prob. 18.33EPCh. 18 - Prob. 18.34EPCh. 18 - Draw the Fischer projection formula for each of...Ch. 18 - Prob. 18.36EPCh. 18 - Prob. 18.37EPCh. 18 - Prob. 18.38EPCh. 18 - Prob. 18.39EPCh. 18 - Prob. 18.40EPCh. 18 - Prob. 18.41EPCh. 18 - Prob. 18.42EPCh. 18 - Prob. 18.43EPCh. 18 - Prob. 18.44EPCh. 18 - Prob. 18.45EPCh. 18 - Prob. 18.46EPCh. 18 - Prob. 18.47EPCh. 18 - Prob. 18.48EPCh. 18 - Prob. 18.49EPCh. 18 - Prob. 18.50EPCh. 18 - Prob. 18.51EPCh. 18 - Prob. 18.52EPCh. 18 - Prob. 18.53EPCh. 18 - Prob. 18.54EPCh. 18 - Prob. 18.55EPCh. 18 - Prob. 18.56EPCh. 18 - Prob. 18.57EPCh. 18 - Prob. 18.58EPCh. 18 - Prob. 18.59EPCh. 18 - Prob. 18.60EPCh. 18 - Prob. 18.61EPCh. 18 - Prob. 18.62EPCh. 18 - Prob. 18.63EPCh. 18 - Prob. 18.64EPCh. 18 - Prob. 18.65EPCh. 18 - Prob. 18.66EPCh. 18 - Prob. 18.67EPCh. 18 - Prob. 18.68EPCh. 18 - Prob. 18.69EPCh. 18 - Prob. 18.70EPCh. 18 - Prob. 18.71EPCh. 18 - Prob. 18.72EPCh. 18 - Prob. 18.73EPCh. 18 - Prob. 18.74EPCh. 18 - Prob. 18.75EPCh. 18 - Prob. 18.76EPCh. 18 - Prob. 18.77EPCh. 18 - Prob. 18.78EPCh. 18 - Prob. 18.79EPCh. 18 - Prob. 18.80EPCh. 18 - Prob. 18.81EPCh. 18 - Prob. 18.82EPCh. 18 - Prob. 18.83EPCh. 18 - Prob. 18.84EPCh. 18 - Prob. 18.85EPCh. 18 - Prob. 18.86EPCh. 18 - Prob. 18.87EPCh. 18 - Prob. 18.88EPCh. 18 - Prob. 18.89EPCh. 18 - Prob. 18.90EPCh. 18 - Prob. 18.91EPCh. 18 - Prob. 18.92EPCh. 18 - Prob. 18.93EPCh. 18 - Prob. 18.94EPCh. 18 - Prob. 18.95EPCh. 18 - Prob. 18.96EPCh. 18 - Prob. 18.97EPCh. 18 - Prob. 18.98EPCh. 18 - Prob. 18.99EPCh. 18 - Prob. 18.100EPCh. 18 - Prob. 18.101EPCh. 18 - Prob. 18.102EPCh. 18 - Prob. 18.103EPCh. 18 - Prob. 18.104EPCh. 18 - For each structure in Problem 18-103, identify the...Ch. 18 - For each structure in Problem 18-104, identify the...Ch. 18 - Prob. 18.107EPCh. 18 - Prob. 18.108EPCh. 18 - Prob. 18.109EPCh. 18 - Prob. 18.110EPCh. 18 - Prob. 18.111EPCh. 18 - Prob. 18.112EPCh. 18 - Prob. 18.113EPCh. 18 - Prob. 18.114EPCh. 18 - Prob. 18.115EPCh. 18 - Prob. 18.116EPCh. 18 - Prob. 18.117EPCh. 18 - Prob. 18.118EPCh. 18 - Prob. 18.119EPCh. 18 - Prob. 18.120EPCh. 18 - Prob. 18.121EPCh. 18 - Prob. 18.122EPCh. 18 - Prob. 18.123EPCh. 18 - Prob. 18.124EPCh. 18 - Prob. 18.125EPCh. 18 - Prob. 18.126EPCh. 18 - Prob. 18.127EPCh. 18 - Prob. 18.128EPCh. 18 - Prob. 18.129EPCh. 18 - Prob. 18.130EPCh. 18 - Prob. 18.131EPCh. 18 - Prob. 18.132EPCh. 18 - Prob. 18.133EPCh. 18 - Prob. 18.134EPCh. 18 - Prob. 18.135EPCh. 18 - Prob. 18.136EPCh. 18 - Prob. 18.137EPCh. 18 - Prob. 18.138EPCh. 18 - Prob. 18.139EPCh. 18 - Prob. 18.140EPCh. 18 - Prob. 18.141EPCh. 18 - Prob. 18.142EPCh. 18 - Prob. 18.143EPCh. 18 - Prob. 18.144EPCh. 18 - Prob. 18.145EPCh. 18 - Prob. 18.146EPCh. 18 - Prob. 18.147EPCh. 18 - Prob. 18.148EPCh. 18 - Prob. 18.149EPCh. 18 - Prob. 18.150EPCh. 18 - Prob. 18.151EPCh. 18 - Prob. 18.152EPCh. 18 - Prob. 18.153EPCh. 18 - Prob. 18.154EPCh. 18 - Prob. 18.155EPCh. 18 - Prob. 18.156EPCh. 18 - Prob. 18.157EPCh. 18 - Prob. 18.158EPCh. 18 - Prob. 18.159EPCh. 18 - Prob. 18.160EPCh. 18 - Prob. 18.161EPCh. 18 - Prob. 18.162EPCh. 18 - Prob. 18.163EPCh. 18 - Prob. 18.164EPCh. 18 - Prob. 18.165EPCh. 18 - Prob. 18.166EPCh. 18 - Prob. 18.167EPCh. 18 - Prob. 18.168EPCh. 18 - Prob. 18.169EPCh. 18 - Prob. 18.170EPCh. 18 - Describe the general features of the cell...Ch. 18 - Prob. 18.172EP
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