Interpretation:
The aldehyde or ketone which gives the given alcohol on reduction with H2 /metal catalyst should be determined.
Concept Introduction:
The carbonyl group of aldehyde and ketone on reduction gives alcohol. The C=O group get reduced to C-OH group. The
Interpretation:
The aldehyde or ketone which gives the given alcohol on reduction with H2 /metal catalyst should be determined.
Concept Introduction:
The carbonyl group of aldehyde and ketone on reduction gives alcohol. The C=O group get reduced to C-OH group. The aldehydes give primary alcohol on reduction and ketones get reduced to secondary alcohol.
Interpretation:
The aldehyde or ketone which gives the given alcohol on reduction with H2 /metal catalyst should be determined.
Concept Introduction:
The carbonyl group of aldehyde and ketone on reduction gives alcohol. The C=O group get reduced to C-OH group. The aldehydes give primary alcohol on reduction and ketones get reduced to secondary alcohol.
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Chapter 17 Solutions
Introduction to General, Organic and Biochemistry
- Problem 17-6 Show the reaction of benzaldehyde with one molecule of methanol to form a hemiacetal and then with a second molecule of methanol to form an acetal.arrow_forwardProblem 2,8 Suggest a plausible arrow-pushing mechanism for the following tautomerization reactions cat. HA OH cat B O NH2 NH2 NIHarrow_forwardPROBLEM 8 How would you convert this diamine to either of these two protected derivatives? MON X₁ H₂N NH₂ x H₂N NHBoc or BocHN XNH,arrow_forward
- PLS ANSWER THIS IS NOT GRADEDarrow_forwardProblem 17-7 Identify all hemiacetals and acetals in the following structures and tell whether each is formed from an aldehyde or a ketone. OH (a) (b) CH3OCH2CH2OCH3 (c)arrow_forwardProblem 19-2 Complete the equation for each hydrolysis reaction. Draw all products as they are ionized under these experimental conditions.arrow_forward
- Problem 23 of 24 Draw the product of the reaction shown below. Ignore inorganic byproducts. OH Na2Cr2O7 JOH H2O, CH3CO2H Submit Select to Drawarrow_forwardProblem 18 of 30 Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following enzyme-catalyzed biological reduction with NADH. Be sure to account for all bond- breaking and bond-making steps. :0: Ï HH :0: NH₂ oi R Select to Add Arrows H I Acid alcohol dehydrogenase X H R Acid H :0: di NH₂ N Submitarrow_forwardWhich of the following cannot be prepared from an ethyl ester (RCOOEt)? Not answer C A) OH C) H OH C OH B) + D) OHarrow_forward
- Problem 15 of 15 Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic steps. Be sure to account for all bond-breaking and bond-making steps. Select to Edit Arrows HCI, CH3CH₂OH H •H Анн H INH HH HH 'H Submit Harrow_forward← Choose the best reagents to complete the following reaction. H CH3CH2CH2NH2, TSOH a Q Problem 21 of 23 A B C D CH3CH2CH2CH2NH2, TSOH CH3CH2CH2NH2, TSOH NH₂OH, TSOH CHỊCHÍCH,CHINH, NGOH Donearrow_forwardProblem 15 of 15 Submit Draw the major product of this reaction. Ignore inorganic byproducts. Assume that the water side product is continuously removed to drive the reaction toward products. (CH2OH)2, TSOH Select to Draw H Qarrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning