(a)
Interpretation:
The structural formula for the product formed by the treatment of Butanal with
Concept Introduction:
Butanal is a compound with four carbon atoms and −CHO group.
The structure of Butanal is as follows:
(b)
Interpretation:
The structural formula for the product formed by the treatment of Butanal with
Concept Introduction:
Butanal is a compound with four carbon atoms and −CHO group.
The structure of Butanal is as follows.
(c)
Interpretation:
The structural formula for the product formed by the treatment of Butanal with Tollen’s reagent should be drawn.
Concept Introduction:
Butanal is an aldehyde and the compound which have four carbons.
The structure of Butanal is as follows.
(d)
Interpretation:
The structural formula for the product formed by the treatment of Butanal with
Concept Introduction:
Butanal is an aldehyde and the compound which have four carbons.
The structure of Butanal is as follows.
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Chapter 17 Solutions
Introduction to General, Organic and Biochemistry
- 17-33 What simple chemical test could you use to distinguish between the members of each pair of com pounds? Tell what you would do, what you would expect to observe, and how you would interpret your experimental observation. (a) Pentanal and 2-pentanone (b) 2-Pentanone and 2-pentanolarrow_forward17-35 Suppose that you take a bottle of benzaldehyde (a liquid, bp 179°C) from a shelf and find a white solid in the bottom of the bottle. The solid turns litmus red; that is, it is acidic. Yet aldehydes are neutral compounds. How can you explain these observations?arrow_forward18-48 4-Aminobenzoic acid is prepared from benzoic acid by the following two steps. Show reagents and experimental conditions to bring about each step.arrow_forward
- 17-3 1 Draw a structural formula for the principal organic product formed when each compound is treated with K2Cr2O7/H2SO4. If there is no reaction, say so. (a) Butanal (b) Benzaldehyde (c) Cyclohexanone (d) Cyclohexanolarrow_forwardDraw line structures of the following compounds and the product you would obtain from the reduction of each.(a) Isopropyl methyl ketone (b) p-Hydroxybenzaldehyde(c) 2-Methylcyclopentanonearrow_forwardWhich, if any, of the following compounds can be prepared by a malonic ester synthesis? Show the alkyl halide you would use in each case. (a) Ethyl pentanoate (c) Ethyl 2-rnethylbutanoate (d) Ethyl 2,2-dimethylpropanoate (b) Ethyl 3-methylbutanoatearrow_forward
- 1. Predict the products or the reaction of (i) phenylacetaldehyde and (ii) acetophenone with the following reagents: (a) NABH4, then H0+ (c) NH2OH, HCI catalyst (e) 2 CH3OH, HCl catalyst (g) (CH3)3P=CH, (b) Tollens' reagent (cl) CHĄMgBr, then H30+ (t) H2NNH2. KOH (h) HCN, KCNarrow_forwardWhich of the following reactions will synthesize phenol from benzene? 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) warm H2SO4 and H2O 1) HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2, HCl, 0-10 oC; 4) CuCN; 5) dilute acid and heat 1) Acetyl chloride & AlCl3; 2) bleach 1) Ph-N2+ + KI; 2) BrMgCH=CH2 in ether, followed by H3O+; 3) warm, conc'd KMnO4 1) Cl-CH(CH3)-CH2CH2CH3 + FeBr3; 2) hot, conc'd KMnO4arrow_forwardExplain why each of the following carboxylic acids cannot be prepared by a malonic ester synthesis: (a) (CH3CCH;COOH; (b) C,H;CH2COOH; (c) (CHa)CCOOH.arrow_forward
- What product will be formed on reaction of propanal with 2-methylpropanal in the presence of NaOH? What products will be formed? Write the name of the reaction also.arrow_forwardPredict the major products formed when benzoyl chloride (PhCOCl) reacts with the following reagents.(a) ethanoarrow_forwardDraw the structural formula of the principal organic product formed when benzonitrile is treated with CH3MgBr followed by work-up with dilute acid.arrow_forward
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