(a) Interpretation: The structure formula for the keto from of enol should be drawn. Concept Introduction: Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

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Answer 1

Question

Chapter 17.5, Problem 17.8P

Interpretation Introduction

(a)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(b)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(c)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

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Please predict the product for the following reactions in a drawn out solution.

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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

Answer 2

Question

Chapter 17.5, Problem 17.8P

Interpretation Introduction

(a)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(b)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(c)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

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Answer 3

Question

Chapter 17.5, Problem 17.8P

Interpretation Introduction

(a)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(b)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(c)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

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Answer 4

Question

Chapter 17.5, Problem 17.8P

Interpretation Introduction

(a)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(b)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(c)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

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Answer 5

Chapter 17.5, Problem 17.8P

Interpretation Introduction

(a)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(b)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Interpretation Introduction

(c)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Answer 6

Chapter 17.5, Problem 17.8P

Interpretation Introduction

(a)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Answer 7

Chapter 17.5, Problem 17.8P

Interpretation Introduction

(a)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure formula for the keto from of enol should be drawn.

Concept Introduction:

Keto and enol form both are present in the equilibrium with each other but differ in the position of hydrogen atom and double bond. These are constitutional isomers and this isomerism is known as keto- enol tautomerism.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 17.2 - Problem 17-1 Wrtie the IUPAC name for each...Ch. 17.2 - Prob. 17.2P Ch. 17.2 - Prob. 17.3P Ch. 17.4 - Prob. 17.4P Ch. 17.4 - Prob. 17.5P Ch. 17.4 - Problem 17-6 Show the reaction of benzaldehyde...Ch. 17.4 - Problem 17-7 Identify all hemiacetals and acetals...Ch. 17.5 - Prob. 17.8P Ch. 17 - 17-9 Answer true or false. (a) The one aldehyde...Ch. 17 - Prob. 17.10P

Solution Summary: The author explains that the structure formula for the keto from of enol should be drawn.

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Chapter 17 Solutions