Chemistry: Matter and Change
1st Edition
ISBN: 9780078746376
Author: Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher: Glencoe/McGraw-Hill School Pub Co
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Chapter 17, Problem 46A
Interpretation Introduction
Interpretation:
The equilibrium constant expression for a heterogeneous equation is to determined.
Concept introduction:
The equilibrium constant is the ratio of concentration of products to the concentration of reactants and heterogeneous reaction is that in which the reactants and products are present in different phases.
Expert Solution & Answer
Answer to Problem 46A
The equilibrium expression for the given reaction is
Keq=[CO2(g)]
Because given reaction is the type of heterogeneous reaction because in this reaction product and reactant are in different phases. So, the concentration of CaO(g) and CaCO3(g) may be assumed to be constant or unity.
Explanation of Solution
The equilibrium constant is the ratio of concentration of products to the concentration of reactants.
A heterogeneous reaction is that in which reactants and product are in the different phases.
The given reversible reaction is
CaCO3(s)⇌CaO(s)+CO2(g)
The equilibrium expression for the given reaction is
Keq=[CaO(s)][CO2(g)][CaCO3(s)]
The concentration of CaO(g) and CaCO3(g) may be assumed to be constant or unity. So, the equilibrium constant becomes
Keq=[CO2(g)]
Reason: Heterogeneous reaction does not include the concentration of pure solids and pure liquids because their concentration remains constant.
Conclusion
The equilibrium expression for the given reaction is
Keq=[CO2(g)]
Because given reaction is the type of heterogeneous reaction because in this reaction product and reactant are in different phases. So, the concentration of CaO(g) and CaCO3(g) may be assumed to be constant or unity.
Chapter 17 Solutions
Chemistry: Matter and Change
Ch. 17.1 - Prob. 1PPCh. 17.1 - Prob. 2PPCh. 17.1 - Prob. 3PPCh. 17.1 - Prob. 4PPCh. 17.1 - Prob. 5PPCh. 17.1 - Prob. 6PPCh. 17.1 - Prob. 7PPCh. 17.1 - Prob. 8SSCCh. 17.1 - Prob. 9SSCCh. 17.1 - Prob. 10SSC
Ch. 17.1 - Prob. 11SSCCh. 17.1 - Prob. 12SSCCh. 17.2 - Prob. 13SSCCh. 17.2 - Prob. 14SSCCh. 17.2 - Prob. 15SSCCh. 17.2 - Prob. 16SSCCh. 17.2 - Prob. 17SSCCh. 17.3 - Prob. 18PPCh. 17.3 - Prob. 19PPCh. 17.3 - Prob. 20PPCh. 17.3 - Prob. 21PPCh. 17.3 - Prob. 22PPCh. 17.3 - Prob. 23PPCh. 17.3 - Prob. 24PPCh. 17.3 - Prob. 25PPCh. 17.3 - Prob. 26PPCh. 17.3 - Prob. 27SSCCh. 17.3 - Prob. 28SSCCh. 17.3 - Prob. 29SSCCh. 17.3 - Prob. 30SSCCh. 17.3 - Prob. 31SSCCh. 17.3 - Prob. 32SSCCh. 17 - Prob. 33ACh. 17 - Prob. 34ACh. 17 - Prob. 35ACh. 17 - Prob. 36ACh. 17 - Prob. 37ACh. 17 - Prob. 38ACh. 17 - Prob. 39ACh. 17 - Prob. 40ACh. 17 - Prob. 41ACh. 17 - Prob. 42ACh. 17 - Prob. 43ACh. 17 - Prob. 44ACh. 17 - Prob. 45ACh. 17 - Prob. 46ACh. 17 - Prob. 47ACh. 17 - Prob. 48ACh. 17 - Prob. 49ACh. 17 - Prob. 50ACh. 17 - Prob. 51ACh. 17 - Prob. 52ACh. 17 - Prob. 53ACh. 17 - Prob. 54ACh. 17 - Prob. 55ACh. 17 - Prob. 56ACh. 17 - Prob. 57ACh. 17 - Prob. 58ACh. 17 - Prob. 59ACh. 17 - Prob. 60ACh. 17 - Prob. 61ACh. 17 - Prob. 62ACh. 17 - Prob. 63ACh. 17 - Prob. 64ACh. 17 - Why are compounds such as sodium chloride usually...Ch. 17 - Prob. 66ACh. 17 - Prob. 67ACh. 17 - Prob. 68ACh. 17 - Prob. 69ACh. 17 - Prob. 70ACh. 17 - Prob. 71ACh. 17 - Prob. 72ACh. 17 - Prob. 73ACh. 17 - Prob. 74ACh. 17 - Prob. 75ACh. 17 - Prob. 76ACh. 17 - Prob. 77ACh. 17 - Prob. 78ACh. 17 - Evaluate this statement: A low value for Keq means...Ch. 17 - Prob. 80ACh. 17 - Prob. 81ACh. 17 - Prob. 82ACh. 17 - Prob. 83ACh. 17 - Prob. 84ACh. 17 - Prob. 85ACh. 17 - Prob. 86ACh. 17 - Prob. 87ACh. 17 - Prob. 88ACh. 17 - Prob. 89ACh. 17 - Prob. 90ACh. 17 - Prob. 91ACh. 17 - Prob. 92ACh. 17 - Prob. 93ACh. 17 - Prob. 94ACh. 17 - Prob. 95ACh. 17 - Prob. 96ACh. 17 - Prob. 97ACh. 17 - Prob. 98ACh. 17 - Prob. 99ACh. 17 - Prob. 100ACh. 17 - Prob. 101ACh. 17 - Prob. 102ACh. 17 - Prob. 103ACh. 17 - Prob. 104ACh. 17 - Prob. 105ACh. 17 - Prob. 1STPCh. 17 - Prob. 2STPCh. 17 - Prob. 3STPCh. 17 - Prob. 4STPCh. 17 - Prob. 5STPCh. 17 - Prob. 6STPCh. 17 - Prob. 7STPCh. 17 - Prob. 8STPCh. 17 - Prob. 9STPCh. 17 - Prob. 10STPCh. 17 - Prob. 11STPCh. 17 - Prob. 12STPCh. 17 - Prob. 13STPCh. 17 - Prob. 14STPCh. 17 - Prob. 15STPCh. 17 - Prob. 16STPCh. 17 - Prob. 17STPCh. 17 - Prob. 18STP
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