Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 17, Problem 40P

Give stereochemical formulas for compounds A–Q:

(a) ( R ) - ( ) - 2 - B u tan o l p y r i d i n e p- t o l u e n e s u l f o n y l c h l o r i d e ( T s C l ) A C N B ( C 5 H 9 N ) H 2 O H 2 S O 4 ( + ) - C ( C 5 H 10 O 2 ) H 2 O ( 1 ) L i A l H 4 ( ) - D ( C 5 H 12 O )

(b) ( R ) - ( ) - 2 - B u tan o l p y r i d i n e P B r 3 E ( C 4 H 9 B r ) C N F ( C 5 H 9 N ) H 2 O H 2 S O 4 ( ) - C ( C 5 H 10 O 2 ) H 2 O ( 1 ) L i A l H 4 ( + ) - D ( C 5 H 12 O )

(c) A C H 3 C O 2 G ( C 6 H 12 O 2 ) H O ( + ) - H ( C 4 H 10 O ) + C H 3 C O 2

(d) ( ) - D P B r 3 J ( C 5 H 11 B r ) E t 2 O M g K ( C 5 H 11 M g B r ) ( 2 ) H 3 O + ( 1 ) C O 2 L ( C 6 H 12 O 2 )

(e)

Chapter 17, Problem 40P, Give stereochemical formulas for compounds AQ: (a)

(f) M H 2 O H 2 S O 4 P ( C 4 H 8 O 5 ) H N O 3 [ O ] meso- t a r t a r i c   a c i d

(g) N H 2 O H 2 S O 4 Q ( C 4 H 8 O 5 ) H N O 3 [ O ] ( ) - t a r t a r i c   a c i d

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Chapter 17 Solutions

Organic Chemistry

Ch. 17 - Prob. 11PPCh. 17 - Practice Problem 17.12 What products would you...Ch. 17 - Practice Problem 17.13 (a) Provide the reagents...Ch. 17 - Prob. 14PPCh. 17 - Practice Problem 17.15 Using decarboxylation...Ch. 17 - Practice Problem 17.16 Diacyl peroxides, ,...Ch. 17 - Prob. 17PCh. 17 - Give an IUPAC systematic or common name for each...Ch. 17 - Prob. 19PCh. 17 - Prob. 20PCh. 17 - 17.21 What major organic product would you expect...Ch. 17 - Prob. 22PCh. 17 - Prob. 23PCh. 17 - Prob. 24PCh. 17 - Prob. 25PCh. 17 - 17.26 What products would you expect to obtain...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - 17.28 Indicate reagents that would accomplish each...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - Prob. 30PCh. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - 17.33 On heating,...Ch. 17 - Prob. 34PCh. 17 - Prob. 35PCh. 17 - 17.36 Show how pentanoic acid can be prepared from...Ch. 17 - 17.37 The active ingredient of the insect...Ch. 17 - Prob. 38PCh. 17 - Prob. 39PCh. 17 - Give stereochemical formulas for compounds AQ:...Ch. 17 - 17.41 -Glyceraldehyde can be transformed into...Ch. 17 - Prob. 42PCh. 17 - Prob. 43PCh. 17 - 17.44 Given here are the NMR spectra and carbonyl...Ch. 17 - 17.45 Compound Y dissolves slowly when warmed...Ch. 17 - Prob. 46PCh. 17 - Prob. 47PCh. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Prob. 50PCh. 17 - Prob. 51PCh. 17 - 17.52 Starting with 1-naphthol, suggest an...Ch. 17 - Suggest a synthesis of ibuprofen (Section 5.11)...Ch. 17 - Prob. 54PCh. 17 - Prob. 55PCh. 17 - Prob. 1LGPCh. 17 - Prob. 2LGPCh. 17 - Prob. 3LGPCh. 17 - Prob. 4LGP
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