Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 17, Problem 17.39E
Interpretation Introduction

Interpretation:

The validation of the statement that on breaking down all the units of all the quantities in equation 17.53 into their basic units, all the units are cancelled out is to be stated.

Concept introduction:

Partition function is defined as the functions of the thermodynamic state variables. It is a pure number and a unitless quantity because it represents the sum of the exponential functions.

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A solution contains 10-3 M (NH4)2CO3 plus 10-3 M CaCO3. (NH4+: pKa 9.26) a) Follow the four steps and list the species and equations that would have to be solved to determine the equilibrium solution composition. (15 pts) b) Prepare a log C-pH diagram for the solution. Use a full sheet of graph paper, and show the ranges 1≤ pH < 13 and -10≤ log C≤ -1. (10 pts) c) Use the graphical approach for the solution pH. What is the concentration of all species? (15 pts)
Keggin structure.

Chapter 17 Solutions

Physical Chemistry

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