Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 17, Problem 17.23E
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The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?
One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.
How does the square root mean square velocity of gas molecules vary with temperature? Illustrate this relationship by plotting the square root mean square velocity of N2 molecules as a function of temperature from T=100 K to T=300 K.
Chapter 17 Solutions
Physical Chemistry
Ch. 17 - Prob. 17.1ECh. 17 - Prob. 17.2ECh. 17 - Prob. 17.3ECh. 17 - Prob. 17.4ECh. 17 - Prob. 17.5ECh. 17 - Prob. 17.6ECh. 17 - Prob. 17.7ECh. 17 - Prob. 17.8ECh. 17 - Prob. 17.9ECh. 17 - Prob. 17.10E
Ch. 17 - Prob. 17.11ECh. 17 - If the ni values are all the same, a shorthand way...Ch. 17 - Prob. 17.13ECh. 17 - Prob. 17.14ECh. 17 - Prob. 17.15ECh. 17 - Prob. 17.16ECh. 17 - Prob. 17.17ECh. 17 - Prob. 17.18ECh. 17 - Prob. 17.19ECh. 17 - Prob. 17.20ECh. 17 - Prob. 17.21ECh. 17 - Prob. 17.22ECh. 17 - Explain why q is a constant for a given system at...Ch. 17 - What is the ratio of ground-state nickel atoms in...Ch. 17 - Ti3+ has the following electronic energy levels:...Ch. 17 - Using the fact that =1/kT, show that equations...Ch. 17 - A one-dimensional particle-in-a-box has a length...Ch. 17 - Prob. 17.28ECh. 17 - Prob. 17.29ECh. 17 - Prob. 17.30ECh. 17 - Prob. 17.31ECh. 17 - What is the value of q at absolute zero? Is it the...Ch. 17 - Prob. 17.33ECh. 17 - Prob. 17.34ECh. 17 - Prob. 17.35ECh. 17 - Prob. 17.36ECh. 17 - Prob. 17.37ECh. 17 - Prob. 17.38ECh. 17 - Prob. 17.39ECh. 17 - Prob. 17.40ECh. 17 - Prob. 17.41ECh. 17 - Prob. 17.42ECh. 17 - What change is there in the Sackur-Tetrode...Ch. 17 - Prob. 17.44ECh. 17 - Prob. 17.45ECh. 17 - Prob. 17.46ECh. 17 - Calculate the thermal de Broglie wavelength of He...Ch. 17 - Prob. 17.48ECh. 17 - Prob. 17.49ECh. 17 - Prob. 17.50ECh. 17 - Prob. 17.51ECh. 17 - Prob. 17.52ECh. 17 - Prob. 17.53ECh. 17 - Use equation 17.56 to determine the change in...Ch. 17 - For an electron that has a velocity of 0.01c where...Ch. 17 - Use the Sackur-Tetrode equation to derive the...Ch. 17 - Prob. 17.57ECh. 17 - Prob. 17.58E
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