Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 17, Problem 17.33E
Interpretation Introduction

Interpretation:

The equation 17.42 is to be derived using equation 17.41 by following the steps outlined in the text.

Concept introduction:

Statistical thermodynamics is used to describe all possible configurations in a system at given physical quantities such as pressure, temperature and number of particles in the system. The important quantity in thermodynamics is partition function that is represented as,

qigieβi

It is also called as canonical ensemble partition function.

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