Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Question
Chapter 17, Problem 17.13E
Interpretation Introduction
Interpretation:
The state of the overall system for grand canonical ensemble is to be stated.
Concept introduction:
The thermodynamic state of a large microscopic system is understood using the statistical
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20. The Brusselator. This hypothetical system was first proposed by a group work-
ing in Brussels [see Prigogine and Lefever (1968)] in connection with spatially
nonuniform chemical patterns. Because certain steps involve trimolecular reac
tions, it is not a model of any real chemical system but rather a prototype that
has been studied extensively. The reaction steps are
A-X.
B+X-Y+D.
2X+ Y-3X,
X-E.
305
It is assumed that concentrations of A, B, D, and E are kept artificially con
stant so that only X and Y vary with time.
(a) Show that if all rate constants are chosen appropriately, the equations de
scribing a Brusselator are:
dt
A-(B+ 1)x + x²y,
dy
=Bx-x²y.
di
Problem 3. Provide a mechanism for the following transformation:
H₂SO A
Me.
Me
Me
Me
Me
You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Chapter 17 Solutions
Physical Chemistry
Ch. 17 - Prob. 17.1ECh. 17 - Prob. 17.2ECh. 17 - Prob. 17.3ECh. 17 - Prob. 17.4ECh. 17 - Prob. 17.5ECh. 17 - Prob. 17.6ECh. 17 - Prob. 17.7ECh. 17 - Prob. 17.8ECh. 17 - Prob. 17.9ECh. 17 - Prob. 17.10E
Ch. 17 - Prob. 17.11ECh. 17 - If the ni values are all the same, a shorthand way...Ch. 17 - Prob. 17.13ECh. 17 - Prob. 17.14ECh. 17 - Prob. 17.15ECh. 17 - Prob. 17.16ECh. 17 - Prob. 17.17ECh. 17 - Prob. 17.18ECh. 17 - Prob. 17.19ECh. 17 - Prob. 17.20ECh. 17 - Prob. 17.21ECh. 17 - Prob. 17.22ECh. 17 - Explain why q is a constant for a given system at...Ch. 17 - What is the ratio of ground-state nickel atoms in...Ch. 17 - Ti3+ has the following electronic energy levels:...Ch. 17 - Using the fact that =1/kT, show that equations...Ch. 17 - A one-dimensional particle-in-a-box has a length...Ch. 17 - Prob. 17.28ECh. 17 - Prob. 17.29ECh. 17 - Prob. 17.30ECh. 17 - Prob. 17.31ECh. 17 - What is the value of q at absolute zero? Is it the...Ch. 17 - Prob. 17.33ECh. 17 - Prob. 17.34ECh. 17 - Prob. 17.35ECh. 17 - Prob. 17.36ECh. 17 - Prob. 17.37ECh. 17 - Prob. 17.38ECh. 17 - Prob. 17.39ECh. 17 - Prob. 17.40ECh. 17 - Prob. 17.41ECh. 17 - Prob. 17.42ECh. 17 - What change is there in the Sackur-Tetrode...Ch. 17 - Prob. 17.44ECh. 17 - Prob. 17.45ECh. 17 - Prob. 17.46ECh. 17 - Calculate the thermal de Broglie wavelength of He...Ch. 17 - Prob. 17.48ECh. 17 - Prob. 17.49ECh. 17 - Prob. 17.50ECh. 17 - Prob. 17.51ECh. 17 - Prob. 17.52ECh. 17 - Prob. 17.53ECh. 17 - Use equation 17.56 to determine the change in...Ch. 17 - For an electron that has a velocity of 0.01c where...Ch. 17 - Use the Sackur-Tetrode equation to derive the...Ch. 17 - Prob. 17.57ECh. 17 - Prob. 17.58E
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