Chemistry for Today: General  Organic  and Biochemistry
Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Chapter 17, Problem 17.28E
Interpretation Introduction

(a)

Interpretation:

Whether the Haworth structure represents an α or a β form is to be stated and the structure of the other anomer is to be drawn.

Concept introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered ring is called furanose.

Interpretation Introduction

(b)

Interpretation:

Whether the Haworth structure represents an α or a β form is to be stated and the structure of the other anomer is to be drawn.

Concept introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered ring is called furanose.

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b. CH3 H3C CH3 CH3 H3C an unexpected product, containing a single 9- membered ring the expected product, containing two fused rings H3C-I (H3C)2CuLi an enolate
b. H3C CH3 1. 2. H3O+ H3C MgBr H3C

Chapter 17 Solutions

Chemistry for Today: General Organic and Biochemistry

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