Problem 17.1P: Write a balanced net ionic equation for the neutralization of equimolar amounts of HNO2 and KOH.... Problem 17.2P: APPLY 16.2 Write balanced net ionic equations for the neutralization of the following acids and... Problem 17.3A: PRACTICE 16.3 Calculate the concentrations of all species present, the pH, and the... Problem 17.4P: APPLY 16.4 Calculate the pH of a solution prepared by mixing equal volumes of 0.20 Mmethylamine (,)... Problem 17.5P: Conceptual PRACTICE 16.5 The following pictures represent initial concentrations in solutions of the... Problem 17.6A: Conceptual APPLY 16.6 The following pictures representinitial concentrations in solutions of a weak... Problem 17.7P: Calculate the pH of 0.100 1 of a buffer solution that is 0.25 M in HF and 0.50 M in NaF with an... Problem 17.8A: Calculate the change in pH when 0.002 mol of HNO3 is added to 0.100 L of a buffer solution that is... Problem 17.9P: PRACTICE 16.10 Use the Henderson-Hasselbalch equation to calculate the pH of a buffer solution... Problem 17.10A: APPLY 16.11 The of the amine group of the amino acid serine is 9.15.
(a) What is the pH of a... Problem 17.11P: PRACTICE 16.12 How would you prepare anbuffer solution that has pH = 10.40?
Problem 17.12A: APPLY 16.13 Suppose you are performing an experiment thatrequires a constant pH of 7.00.
(a) Which... Problem 17.13P: A 40.0 mL volume of 0.100 M HCl is titrated with 0.100 M NaOH. Calculate the pH of the solution... Problem 17.14A: APPLY 16.15 A 40.0 mL volume of 0.100 M NaOH is titrated with 0.0500 M HCI. Calculate the pH after... Problem 17.15P: What is the pH at the equivalence point in the titration of 100.0 mL of 0.0500 M HOCl (Ka=3.5108)... Problem 17.16A: The following pictures represent solutions at various points in the titration of a weak acid HA with... Problem 17.17P: Assume that 40.0 mL of 0.0800 MH2SO3(Ka1=1.5102,Ka2=6.3108) is titrated with 0.160 M NaOH. Calculate... Problem 17.18A: Assume that 40.0 mL of a 0.0250 M solution of the protonated form of the amino acid valine ( H2A+ )... Problem 17.19P: Write the equilibrium-constant expression for KspofCa3(PO4)2 Problem 17.20A: The following pictures represent solutions of three silver salts: AgX, AgY, and AgZ. The pictures... Problem 17.21P Problem 17.22A: Ca2, which causes clotting, is removed from donated blood by precipitation with sodium oxalate... Problem 17.23P: What is the molar solubility of Ag2CrO4 in water at 25 °C? Ksp=1.11012 Problem 17.24A: Prior to having an X-ray exam of the upper gastrointestinal tract, a patient drinks an aqueous... Problem 17.25P: Calculate the molar solubility of MgF2 , in 0.10MMgCl2at25C. Problem 17.26A: Calculate the molar solubility of Zn(OH)2 , in a solution buffered at pH = 11 at 25 °C.... Problem 17.27P: In an excess of NH3(aq),Cu2+ ion forms a deep blue complex ion, Cu(NH3)42+ , which has a formation... Problem 17.28A: Cyanide ion is used in gold mining because it forms a soluble complex ion with Au+ . To study the... Problem 17.29P Problem 17.30A Problem 17.31P Problem 17.32A: Will a precipitate form on mixing 25 m1 of 1.0103MMnSO4 , 25 mL of 1.0103MFeSO4 M , and 200 mL of a... Problem 17.33P Problem 17.34P Problem 17.35P: HCO3 And CO32 are the primary ions in the ocean that act as a buffer against pH change due to acid... Problem 17.36P: Coral and the shells of marine organisms are made of calcium carbonate. Calculate the molar... Problem 17.37P: The following reactions represent the dissolution of CaCO3 due to increased acidity from CO2... Problem 17.38CP Problem 17.39CP: The following pictures represent initial concentrations in solutions that contain a weak acid HA (... Problem 17.40CP Problem 17.41CP: The following plot shows two pH titration curves, each representing the titration of 50.0 mL of... Problem 17.42CP Problem 17.43CP: The following pictures represent solutions at various stages in the titration of a weak diprotic... Problem 17.44CP Problem 17.45CP Problem 17.46CP Problem 17.47SP: 16.50 Is the pH greater than, equal to, or less than 7 after the neutralization of each of the... Problem 17.48SP: Is the pH greater than, equal to, or less than 7 after the neutralization of each of the following... Problem 17.49SP Problem 17.50SP Problem 17.51SP Problem 17.52SP Problem 17.53SP: 16.56 The equilibrium constant for the neutralization of lactic acid() and urea () is . What is ... Problem 17.54SP: 16.57 The equilibrium constant for the neutralization of boric acid() and caffeine () is 24. What... Problem 17.55SP: 16.58 Does the pH increase, decrease, or remain the same on the addition of each of the... Problem 17.56SP: 16.59 Does the pH increase, decrease, or remain the same on the addition of each of the... Problem 17.57SP: 16.60 Calculate the pH of a solution that is 0.25 M in HF and 0.10 M inNaF.
Problem 17.58SP Problem 17.59SP Problem 17.60SP: The pH of a solution of NH3 and NH4Br is 8.90. What is the molarity of NH4Br if the molarity of NH3... Problem 17.61SP Problem 17.62SP Problem 17.63SP Problem 17.64SP: Which of the following gives a buffer solution when equal volumes of the two solutions are mixed?... Problem 17.65SP Problem 17.66SP Problem 17.67SP Problem 17.68SP: Calculate the pH of a buffer solution prepared by dissolving 4.2 g of and 5.3 g of Na2CO3 in 0.20 L... Problem 17.69SP Problem 17.70SP: Calculate the pH of 0.375 L of a 0.18 M acetic acid—0.29 M sodium acetate buffer before and after... Problem 17.71SP Problem 17.72SP: A food chemist studying the formation of lactic acid in sour milk prepares buffer that is 0.58 M in... Problem 17.73SP Problem 17.74SP Problem 17.75SP Problem 17.76SP: Give a recipe for preparing a CH3CO2HCH3C02NA Na buffer solution that has pH = 4.44. Problem 17.77SP Problem 17.78SP Problem 17.79SP: Consider a buffer solution that contains equal concentrations of H2PO4 and HPO42 . Will the pH... Problem 17.80SP: Calculate the concentrations of NH4+ and NH3 and the pH in a solution prepared by mixing 20.0 g of... Problem 17.81SP Problem 17.82SP: Make a rough plot of pH versus milliliters of acid added for the titration of 50.0 mL of 1.0 M NaOH... Problem 17.83SP Problem 17.84SP: Consider the titration of 50.0 mL of 0.116 M NaOH with 0.0750 M HCI. Calculate the pH after the... Problem 17.85SP Problem 17.86SP: Consider the titration of 25.0 mL of 0.200 MHCO2H with 0.250 M NaOH. How many milliliters of base... Problem 17.87SP: On the same graph, sketch pH titration curves for the titration of (1) a strong acid with a strong... Problem 17.88SP Problem 17.89SP: A 100.0 mL sample of 0.100 M methylamine ( CH3NH2,kb=3.7104 ) is titrated with 0.250 M HNO3 .... Problem 17.90SP: A 50.0 mL sample of 0.250 M ammonia ( NH3,Kb=1.8105 ) is titrated with 0.250 M HNO3 . Calculate the... Problem 17.91SP Problem 17.92SP Problem 17.93SP Problem 17.94SP: What is the pH at the equivalence point for the titration of 0.20 M solutions of the following acids... Problem 17.95SP: Consider the titration of 50.0 mL of a 0.100 M solution of the protonated form of the amino acid... Problem 17.96SP Problem 17.97SP Problem 17.98SP: The titration of 0.02500 L of a diprotic acid solution with 0.1000 M NaOH requires 34.72 mL of... Problem 17.99SP Problem 17.100SP Problem 17.101SP Problem 17.102SP Problem 17.103SP Problem 17.104SP Problem 17.105SP Problem 17.106SP: Use the following solubility data to calculate a value of Ksp for each compound. (a) CdCO3;1.0106M... Problem 17.107SP Problem 17.108SP Problem 17.109SP Problem 17.110SP Problem 17.111SP Problem 17.112SP Problem 17.113SP: Which of the following compounds are more soluble in acidic solution than in pure water? Write a... Problem 17.114SP Problem 17.115SP: Consider saturated solutions of the slightly soluble salt AgBr Is the solubility of AgBr increased,... Problem 17.116SP Problem 17.117SP: Is the solubility of Zn(OH)2 , increased, decreased, or unchanged on addition of each of the... Problem 17.118SP: Is the solubility of Fe(OH)3 increased, decreased, or unchanged on addition of each of the following... Problem 17.119SP Problem 17.120SP Problem 17.121SP Problem 17.122SP Problem 17.123SP Problem 17.124SP: Calculate the molar solubility of Cr(OH)3 in 0.50 M NaOH; kf for Cr(OH)4 is 8 1029 Problem 17.125SP: Zinc hydroxide, Zn(OH)2 = (kSP=4.11017) , is nearly insoluble in water but is more soluble in strong... Problem 17.126SP Problem 17.127SP Problem 17.128SP: “Hard” water contains alkaline earth cations such as Ca2+ , which reacts with CO32 to form insoluble... Problem 17.129SP Problem 17.130SP Problem 17.131SP Problem 17.132SP Problem 17.133SP Problem 17.134SP Problem 17.135SP Problem 17.136SP: Using the qualitative analysis flowchart in Figure 17.18, tell how you could separate the following... Problem 17.137SP: Give a method for separating the following pairs of ions by the addition of no more than two... Problem 17.138SP Problem 17.139SP Problem 17.140MP Problem 17.141MP: Calculate the molar solubility of MnS in a 0.30 M NH4CI0.50MNH3 ; buffer solution that is saturated... Problem 17.142MP Problem 17.143MP: A 100.0 mL sample of a solution that is 0.100 M in HCI and 0.100 M in HCN is titrated with 0.100 M... Problem 17.144MP: A 0.0100mol sample of solid Cd(OH)2(Ksp=5.31015) in 100.0 mL of water is titrated with 0.100 M. HNO3... Problem 17.145MP: One type of kidney stone is a precipitate of calcium oxalate ( CaC2O4,Ksp=2.3109 ). A urine sample... Problem 17.146MP Problem 17.147MP: Ethylenediamine ( NH2CH2CH2NH2 , abbreviated en) is an organic base that can accept two protons: en(... Problem 17.148MP: A 40.0 mL sample of a mixture of HCI and H3PO4 was titrated with 0.100 M NaOH. The first equivalence... Problem 17.149MP: A 1.000 L sample of HCI gas at 25 °C and 732.0 mm Hg was absorbed completely in an aqueous solution... Problem 17.150MP Problem 17.151MP: Consider the reaction that occurs on mixing 50.0 mL of 0.560 M NaHCO3 and 50.0 mL of 0.400 M NaOH at... Problem 17.152MP: In qualitative analysis, Ca2+ and Ba2+ are separated from Na+,K+andMg2+ , K, and Mg2 by adding... Problem 17.153MP: A railroad tank car derails and spills 36 tons of concentrated sulfuric acid. The acid is 98.0 mass%... Problem 17.154MP: Some progressive hair coloring products marketed to men, such as Grecian Formula 16, contain lead... format_list_bulleted