(a) Interpretation: The molar solubility of Ag 2 CO 3 is to be calculated. Concept introduction: Solubility product is equilibrium constant for reaction that occurs when an ionic compound is dissolved to produce its constituent ions. It is represented by K sp . Consider A x B y to be an ionic compound. Its dissociation occurs as follows: A x B y ⇌ x A y + + y A x − The expression for its K sp is as follows: K sp = [ A y + ] x [ B x − ] y
(a) Interpretation: The molar solubility of Ag 2 CO 3 is to be calculated. Concept introduction: Solubility product is equilibrium constant for reaction that occurs when an ionic compound is dissolved to produce its constituent ions. It is represented by K sp . Consider A x B y to be an ionic compound. Its dissociation occurs as follows: A x B y ⇌ x A y + + y A x − The expression for its K sp is as follows: K sp = [ A y + ] x [ B x − ] y
Solution Summary: The author explains how the molar solubility of Ag_2TextCO3 is to be calculated.
The molar solubility of Ag2CO3 is to be calculated.
Concept introduction:
Solubility product is equilibrium constant for reaction that occurs when an ionic compound is dissolved to produce its constituent ions. It is represented by Ksp. Consider AxBy to be an ionic compound. Its dissociation occurs as follows:
AxBy⇌xAy++yAx−
The expression for its Ksp is as follows:
Ksp=[Ay+]x[Bx−]y
Interpretation Introduction
(b)
Interpretation:
The molar solubility of CuBr is to be calculated.
Concept introduction:
Solubility product is equilibrium constant for reaction that occurs when an ionic compound is dissolved to produce its constituent ions. It is represented by Ksp. Consider AxBy to be an ionic compound. Its dissociation occurs as follows:
AxBy⇌xAy++yAx−
The expression for its Ksp is as follows:
Ksp=[Ay+]x[Bx−]y
Interpretation Introduction
(c)
Interpretation:
The molar solubility of Cu3(PO4)2 is to be calculated.
Concept introduction:
Solubility product is equilibrium constant for reaction that occurs when an ionic compound is dissolved to produce its constituent ions. It is represented by Ksp. Consider AxBy to be an ionic compound. Its dissociation occurs as follows:
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell