LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
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Textbook Question
Chapter 17, Problem 17.7P
Calculate the pH of 0.100 1 of a buffer solution that is 0.25 M in HF and 0.50 M in NaF with an initial pH of 3.76 after the addition of 0.004 moI of KOH.
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6. (6 points) Suggest an efficient synthesis for the following transformation. Draw the major product at each
step and indicate all reagents used.
Br
میں ممل
Show work with explanation needed. don't give Ai generated solution
Explain the similarities and differences between a voltaic andelectrolytic cell. Be sure to discuss how electrical energy and chemical energy areexchanged in a redox reaction.
What results did this experiment end up with whether this lab was successful or not of the electrochemistry redox reaction (Oxidation Reduction) experiment?
The results:
Part 1: Percent Error Calculation for Voltaic Cells
To calculate the percent error, use the formula:
Percent Error=Theoretical Value∣Observed Value−Theoretical Value∣×100
Theoretical Voltages for Voltaic Cells
To calculate the percent error, we first need the theoretical standard electrode potentials for the voltaic cells:
Zn/Cu:
EZn2+/Zn = −0.76 V
ECu2+/Cu = +0.34 V
Theoretical: Ecell =0.34−(−0.76) = 1.10 V
Zn/Al:
EAl3+/Al = −1.66 V
Theoretical: Ecell = −1.66−(−0.76) = −0.90 V
Zn/Ag:
EAg+/Ag = +0.80 V
Theoretical: Ecell = 0.80−(−0.76) = 1.56 V
Al/Cu:
Theoretical: Ecell = 0.34−(−1.66) = 2.00 V
Ag/Cu:
Theoretical: Ecell = 0.34−0.80 =…
Chapter 17 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
Ch. 17 - Write a balanced net ionic equation for the...Ch. 17 - APPLY 16.2 Write balanced net ionic equations for...Ch. 17 - PRACTICE 16.3 Calculate the concentrations of all...Ch. 17 - APPLY 16.4 Calculate the pH of a solution prepared...Ch. 17 - Conceptual PRACTICE 16.5 The following pictures...Ch. 17 - Conceptual APPLY 16.6 The following pictures...Ch. 17 - Calculate the pH of 0.100 1 of a buffer solution...Ch. 17 - Calculate the change in pH when 0.002 mol of HNO3...Ch. 17 - PRACTICE 16.10 Use the Henderson-Hasselbalch...Ch. 17 - APPLY 16.11 The of the amine group of the amino...
Ch. 17 - PRACTICE 16.12 How would you prepare anbuffer...Ch. 17 - APPLY 16.13 Suppose you are performing an...Ch. 17 - A 40.0 mL volume of 0.100 M HCl is titrated with...Ch. 17 - APPLY 16.15 A 40.0 mL volume of 0.100 M NaOH is...Ch. 17 - What is the pH at the equivalence point in the...Ch. 17 - The following pictures represent solutions at...Ch. 17 - Assume that 40.0 mL of 0.0800...Ch. 17 - Assume that 40.0 mL of a 0.0250 M solution of the...Ch. 17 - Write the equilibrium-constant expression for...Ch. 17 - The following pictures represent solutions of...Ch. 17 - Prob. 17.21PCh. 17 - Ca2, which causes clotting, is removed from...Ch. 17 - What is the molar solubility of Ag2CrO4 in water...Ch. 17 - Prior to having an X-ray exam of the upper...Ch. 17 - Calculate the molar solubility of MgF2 , in...Ch. 17 - Calculate the molar solubility of Zn(OH)2 , in a...Ch. 17 - In an excess of NH3(aq),Cu2+ ion forms a deep blue...Ch. 17 - Cyanide ion is used in gold mining because it...Ch. 17 - Prob. 17.29PCh. 17 - Prob. 17.30ACh. 17 - Prob. 17.31PCh. 17 - Will a precipitate form on mixing 25 m1 of...Ch. 17 - Prob. 17.33PCh. 17 - Prob. 17.34PCh. 17 - HCO3 And CO32 are the primary ions in the ocean...Ch. 17 - Coral and the shells of marine organisms are made...Ch. 17 - The following reactions represent the dissolution...Ch. 17 - Prob. 17.38CPCh. 17 - The following pictures represent initial...Ch. 17 - Prob. 17.40CPCh. 17 - The following plot shows two pH titration curves,...Ch. 17 - Prob. 17.42CPCh. 17 - The following pictures represent solutions at...Ch. 17 - Prob. 17.44CPCh. 17 - Prob. 17.45CPCh. 17 - Prob. 17.46CPCh. 17 - 16.50 Is the pH greater than, equal to, or less...Ch. 17 - Is the pH greater than, equal to, or less than 7...Ch. 17 - Prob. 17.49SPCh. 17 - Prob. 17.50SPCh. 17 - Prob. 17.51SPCh. 17 - Prob. 17.52SPCh. 17 - 16.56 The equilibrium constant for the...Ch. 17 - 16.57 The equilibrium constant for the...Ch. 17 - 16.58 Does the pH increase, decrease, or remain...Ch. 17 - 16.59 Does the pH increase, decrease, or remain...Ch. 17 - 16.60 Calculate the pH of a solution that is 0.25...Ch. 17 - Prob. 17.58SPCh. 17 - Prob. 17.59SPCh. 17 - The pH of a solution of NH3 and NH4Br is 8.90....Ch. 17 - Prob. 17.61SPCh. 17 - Prob. 17.62SPCh. 17 - Prob. 17.63SPCh. 17 - Which of the following gives a buffer solution...Ch. 17 - Prob. 17.65SPCh. 17 - Prob. 17.66SPCh. 17 - Prob. 17.67SPCh. 17 - Calculate the pH of a buffer solution prepared by...Ch. 17 - Prob. 17.69SPCh. 17 - Calculate the pH of 0.375 L of a 0.18 M acetic...Ch. 17 - Prob. 17.71SPCh. 17 - A food chemist studying the formation of lactic...Ch. 17 - Prob. 17.73SPCh. 17 - Prob. 17.74SPCh. 17 - Prob. 17.75SPCh. 17 - Give a recipe for preparing a CH3CO2HCH3C02NA Na...Ch. 17 - Prob. 17.77SPCh. 17 - Prob. 17.78SPCh. 17 - Consider a buffer solution that contains equal...Ch. 17 - Calculate the concentrations of NH4+ and NH3 and...Ch. 17 - Prob. 17.81SPCh. 17 - Make a rough plot of pH versus milliliters of acid...Ch. 17 - Prob. 17.83SPCh. 17 - Consider the titration of 50.0 mL of 0.116 M NaOH...Ch. 17 - Prob. 17.85SPCh. 17 - Consider the titration of 25.0 mL of 0.200 MHCO2H...Ch. 17 - On the same graph, sketch pH titration curves for...Ch. 17 - Prob. 17.88SPCh. 17 - A 100.0 mL sample of 0.100 M methylamine (...Ch. 17 - A 50.0 mL sample of 0.250 M ammonia (...Ch. 17 - Prob. 17.91SPCh. 17 - Prob. 17.92SPCh. 17 - Prob. 17.93SPCh. 17 - What is the pH at the equivalence point for the...Ch. 17 - Consider the titration of 50.0 mL of a 0.100 M...Ch. 17 - Prob. 17.96SPCh. 17 - Prob. 17.97SPCh. 17 - The titration of 0.02500 L of a diprotic acid...Ch. 17 - Prob. 17.99SPCh. 17 - Prob. 17.100SPCh. 17 - Prob. 17.101SPCh. 17 - Prob. 17.102SPCh. 17 - Prob. 17.103SPCh. 17 - Prob. 17.104SPCh. 17 - Prob. 17.105SPCh. 17 - Use the following solubility data to calculate a...Ch. 17 - Prob. 17.107SPCh. 17 - Prob. 17.108SPCh. 17 - Prob. 17.109SPCh. 17 - Prob. 17.110SPCh. 17 - Prob. 17.111SPCh. 17 - Prob. 17.112SPCh. 17 - Which of the following compounds are more soluble...Ch. 17 - Prob. 17.114SPCh. 17 - Consider saturated solutions of the slightly...Ch. 17 - Prob. 17.116SPCh. 17 - Is the solubility of Zn(OH)2 , increased,...Ch. 17 - Is the solubility of Fe(OH)3 increased, decreased,...Ch. 17 - Prob. 17.119SPCh. 17 - Prob. 17.120SPCh. 17 - Prob. 17.121SPCh. 17 - Prob. 17.122SPCh. 17 - Prob. 17.123SPCh. 17 - Calculate the molar solubility of Cr(OH)3 in 0.50...Ch. 17 - Zinc hydroxide, Zn(OH)2 = (kSP=4.11017) , is...Ch. 17 - Prob. 17.126SPCh. 17 - Prob. 17.127SPCh. 17 - “Hard” water contains alkaline earth cations such...Ch. 17 - Prob. 17.129SPCh. 17 - Prob. 17.130SPCh. 17 - Prob. 17.131SPCh. 17 - Prob. 17.132SPCh. 17 - Prob. 17.133SPCh. 17 - Prob. 17.134SPCh. 17 - Prob. 17.135SPCh. 17 - Using the qualitative analysis flowchart in Figure...Ch. 17 - Give a method for separating the following pairs...Ch. 17 - Prob. 17.138SPCh. 17 - Prob. 17.139SPCh. 17 - Prob. 17.140MPCh. 17 - Calculate the molar solubility of MnS in a 0.30 M...Ch. 17 - Prob. 17.142MPCh. 17 - A 100.0 mL sample of a solution that is 0.100 M in...Ch. 17 - A 0.0100mol sample of solid Cd(OH)2(Ksp=5.31015)...Ch. 17 - One type of kidney stone is a precipitate of...Ch. 17 - Prob. 17.146MPCh. 17 - Ethylenediamine ( NH2CH2CH2NH2 , abbreviated en)...Ch. 17 - A 40.0 mL sample of a mixture of HCI and H3PO4 was...Ch. 17 - A 1.000 L sample of HCI gas at 25 °C and 732.0 mm...Ch. 17 - Prob. 17.150MPCh. 17 - Consider the reaction that occurs on mixing 50.0...Ch. 17 - In qualitative analysis, Ca2+ and Ba2+ are...Ch. 17 - A railroad tank car derails and spills 36 tons of...Ch. 17 - Some progressive hair coloring products marketed...
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- 1) List ALL the chemicals you are going to use or encounter for electrochemistry redox reaction (Oxidation Reduction) experiment. If you are working with any materials that have specific hazards or safety concerns list them. 2) List out the glassware, tools, equipment and other materials you think you are going to need to complete the electrochemistry redox reaction (Oxidation Reduction) experiment. Be specific.arrow_forwardIn this section, you should record any visual observations you make (colors, appearances of water, physical states, etc) for electrochemistry redox reaction (Oxidation Reduction)experiment. You should also record any numeric observations (masses, volumes, concentrations).Make sure they are organized and labeled so it is clear what the observation of electrochemistry redox reaction (Oxidation Reduction)experiment. Here is the data for the electrochemistry redox reaction (Oxidation Reduction)experiment: Part 1 was testing the observed vs theoretical cell potentials for the following voltaic cells: Zn/Cu reading was 0.914 Zn/Al reading was 0.210 Zn/Ag reading was 1.330 Al/Cu reading was 0.672 Ag/Cu reading was 0.413 Ag/Al reading was 1.000 Part 2 of the experiment was constructed an electrolytic cell using 2.008 grams of KI in about 100mL of DI water. Then measured the pH of the reaction mixture which was 5.22 with soultion in plain water and 10.74 with soultion added.arrow_forwardDescribe the topics studying for the electrochemistry redox reaction (Oxidation Reduction) experiment. What is the main point of this experiment? Why are we doing it?What should we get out of it?arrow_forward
- For the second part of the experiment, I constructed an electrolytic cell using 2.008 grams of KI in about 100mL of DI water. I measured the pH of the reaction mixture which was 5.22 with soultion in plain water and 10.74 with soultion added. Calculate using your measured pH values at the beginning and end of the reaction, determine the mass of I2 producedarrow_forwardExplain the mechanism and show the stepsarrow_forwardCan you explain the mechanism and show the stepsarrow_forward
- Draw the product of the reaction shown below. Ignore inorganic byproducts. If the reaction results in a mixture of ortho and para isomers, draw only the para-product. CH3C(O)CI AlCl3 Drawingarrow_forwardCan you explain it? How to find the answer? And the various factors that involved E2? What is the difference between the options? What determine nucleophile is better in protic/aproticarrow_forwardExplain each examples and the options and why they are not the answerarrow_forward
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