GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
7th Edition
ISBN: 9781305866966
Author: STOKER
Publisher: CENGAGE L
Question
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Chapter 17, Problem 17.105EP

(a)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  1

Amides are also classified as primary, secondary, and tertiary amide.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  2

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  3

Amides are also classified as primary, secondary, and tertiary amide.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  4

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  5

Amides are also classified as primary, secondary, and tertiary amide.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  6

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be classified as an amine, an amide, or both amine and amide.

Concept Introduction:

Organic compounds are the important basis of life.  They include gasoline, coal, dyes, and clothing fibers etc.  The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds.  Organic compounds are found in earth also apart from living organisms.  All the organic compounds contain the element carbon.  Urea was synthesized in the laboratory which is an organic compound.

Organic compounds contain heteroatom also.  Some of them are nitrogen, sulfur, oxygen etc.  Nitrogen containing organic compounds are of two important types and they are amines, amides.

Amines are organic compounds that contain a nitrogen atom that is bonded to a hydrocarbon chain.

One of the carboxylic acid derivatives is amide.  In this the carboxyl OH group is replaced by an amino or a substituted amino group.  The functional group of amide can be given as,

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  7

Amides are also classified as primary, secondary, and tertiary amide.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.105EP , additional homework tip  8

Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms.  Primary amides are also known as unsubstituted amides.

Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group.  Secondary amides are also known as monosubstituted amides.

Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups.  Tertiary amides are also known as disubstituted amides.

Apart from linear amides, there are also cyclic amides.  They are formed by intramolecular condensation.  Cyclic amides are also known as lactams.

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Write the names for the amines using the naming styles taught in the McMurry text. H2 H3C-N-C-CH3 name: H2 H2 H3C-C-Ņ-c-CH3 H name: These compounds are amines.
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Draw structural formulas for all the amines having the formula C3H9N. Classify each as either a primary amine, a secondary amine, or a tertiary amine.

Chapter 17 Solutions

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP

Ch. 17.4 - Prob. 1QQCh. 17.4 - Prob. 2QQCh. 17.5 - Prob. 1QQCh. 17.5 - Prob. 2QQCh. 17.5 - Prob. 3QQCh. 17.6 - Prob. 1QQCh. 17.6 - Prob. 2QQCh. 17.6 - Prob. 3QQCh. 17.7 - Prob. 1QQCh. 17.7 - Prob. 2QQCh. 17.7 - Prob. 3QQCh. 17.8 - Prob. 1QQCh. 17.8 - Prob. 2QQCh. 17.8 - Prob. 3QQCh. 17.8 - Prob. 4QQCh. 17.9 - Prob. 1QQCh. 17.9 - Prob. 2QQCh. 17.10 - Prob. 1QQCh. 17.10 - Prob. 2QQCh. 17.10 - Prob. 3QQCh. 17.10 - Prob. 4QQCh. 17.11 - Prob. 1QQCh. 17.11 - Prob. 2QQCh. 17.11 - Prob. 3QQCh. 17.12 - Prob. 1QQCh. 17.12 - Prob. 2QQCh. 17.12 - Prob. 3QQCh. 17.12 - Prob. 4QQCh. 17.13 - Prob. 1QQCh. 17.13 - Prob. 2QQCh. 17.13 - Prob. 3QQCh. 17.13 - Prob. 4QQCh. 17.14 - Prob. 1QQCh. 17.14 - Prob. 2QQCh. 17.14 - Prob. 3QQCh. 17.15 - Prob. 1QQCh. 17.15 - Prob. 2QQCh. 17.16 - Prob. 1QQCh. 17.16 - Prob. 2QQCh. 17.16 - Prob. 3QQCh. 17.17 - Prob. 1QQCh. 17.17 - Prob. 2QQCh. 17.17 - Prob. 3QQCh. 17.18 - Prob. 1QQCh. 17.18 - Prob. 2QQCh. 17.18 - Prob. 3QQCh. 17.19 - Prob. 1QQCh. 17.19 - Prob. 2QQCh. 17.19 - Prob. 3QQCh. 17.19 - Prob. 4QQCh. 17 - Prob. 17.1EPCh. 17 - Prob. 17.2EPCh. 17 - Prob. 17.3EPCh. 17 - Prob. 17.4EPCh. 17 - Prob. 17.5EPCh. 17 - Prob. 17.6EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Prob. 17.9EPCh. 17 - Prob. 17.10EPCh. 17 - Prob. 17.11EPCh. 17 - Prob. 17.12EPCh. 17 - Prob. 17.13EPCh. 17 - Prob. 17.14EPCh. 17 - Prob. 17.15EPCh. 17 - Assign a common name to each of the following...Ch. 17 - Prob. 17.17EPCh. 17 - Prob. 17.18EPCh. 17 - Prob. 17.19EPCh. 17 - Prob. 17.20EPCh. 17 - Prob. 17.21EPCh. 17 - Prob. 17.22EPCh. 17 - Prob. 17.23EPCh. 17 - Prob. 17.24EPCh. 17 - Prob. 17.25EPCh. 17 - Prob. 17.26EPCh. 17 - Prob. 17.27EPCh. 17 - Prob. 17.28EPCh. 17 - Prob. 17.29EPCh. 17 - Prob. 17.30EPCh. 17 - Prob. 17.31EPCh. 17 - Prob. 17.32EPCh. 17 - Prob. 17.33EPCh. 17 - Prob. 17.34EPCh. 17 - Determine the maximum number of hydrogen bonds...Ch. 17 - Prob. 17.36EPCh. 17 - Prob. 17.37EPCh. 17 - Prob. 17.38EPCh. 17 - Prob. 17.39EPCh. 17 - Prob. 17.40EPCh. 17 - Prob. 17.41EPCh. 17 - Prob. 17.42EPCh. 17 - Prob. 17.43EPCh. 17 - Prob. 17.44EPCh. 17 - Prob. 17.45EPCh. 17 - Prob. 17.46EPCh. 17 - Prob. 17.47EPCh. 17 - Prob. 17.48EPCh. 17 - Prob. 17.49EPCh. 17 - Prob. 17.50EPCh. 17 - Prob. 17.51EPCh. 17 - Prob. 17.52EPCh. 17 - Prob. 17.53EPCh. 17 - Prob. 17.54EPCh. 17 - Prob. 17.55EPCh. 17 - Prob. 17.56EPCh. 17 - Prob. 17.57EPCh. 17 - Prob. 17.58EPCh. 17 - Prob. 17.59EPCh. 17 - Prob. 17.60EPCh. 17 - Prob. 17.61EPCh. 17 - Prob. 17.62EPCh. 17 - Prob. 17.63EPCh. 17 - Prob. 17.64EPCh. 17 - Prob. 17.65EPCh. 17 - Prob. 17.66EPCh. 17 - Prob. 17.67EPCh. 17 - Prob. 17.68EPCh. 17 - Prob. 17.69EPCh. 17 - Prob. 17.70EPCh. 17 - Prob. 17.71EPCh. 17 - Prob. 17.72EPCh. 17 - Prob. 17.73EPCh. 17 - Prob. 17.74EPCh. 17 - Prob. 17.75EPCh. 17 - Prob. 17.76EPCh. 17 - Prob. 17.77EPCh. 17 - Prob. 17.78EPCh. 17 - Prob. 17.79EPCh. 17 - Prob. 17.80EPCh. 17 - Prob. 17.81EPCh. 17 - Prob. 17.82EPCh. 17 - Prob. 17.83EPCh. 17 - Prob. 17.84EPCh. 17 - Prob. 17.85EPCh. 17 - Prob. 17.86EPCh. 17 - Prob. 17.87EPCh. 17 - Prob. 17.88EPCh. 17 - Prob. 17.89EPCh. 17 - Prob. 17.90EPCh. 17 - Prob. 17.91EPCh. 17 - Prob. 17.92EPCh. 17 - Prob. 17.93EPCh. 17 - Prob. 17.94EPCh. 17 - Prob. 17.95EPCh. 17 - Prob. 17.96EPCh. 17 - Prob. 17.97EPCh. 17 - Prob. 17.98EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the amides in Problem 17-101 as a...Ch. 17 - Prob. 17.104EPCh. 17 - Prob. 17.105EPCh. 17 - Prob. 17.106EPCh. 17 - Prob. 17.107EPCh. 17 - Prob. 17.108EPCh. 17 - Prob. 17.109EPCh. 17 - Prob. 17.110EPCh. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Prob. 17.113EPCh. 17 - Prob. 17.114EPCh. 17 - Prob. 17.115EPCh. 17 - Prob. 17.116EPCh. 17 - Prob. 17.117EPCh. 17 - Prob. 17.118EPCh. 17 - Prob. 17.119EPCh. 17 - What is the relationship between the acronym DEET...Ch. 17 - Prob. 17.121EPCh. 17 - Prob. 17.122EPCh. 17 - Prob. 17.123EPCh. 17 - Prob. 17.124EPCh. 17 - Prob. 17.125EPCh. 17 - Prob. 17.126EPCh. 17 - Prob. 17.127EPCh. 17 - Prob. 17.128EPCh. 17 - Prob. 17.129EPCh. 17 - Prob. 17.130EPCh. 17 - Prob. 17.131EPCh. 17 - Prob. 17.132EPCh. 17 - Prob. 17.133EPCh. 17 - Prob. 17.134EPCh. 17 - Prob. 17.135EPCh. 17 - Prob. 17.136EPCh. 17 - Prob. 17.137EPCh. 17 - Prob. 17.138EPCh. 17 - Prob. 17.139EPCh. 17 - Prob. 17.140EPCh. 17 - Prob. 17.141EPCh. 17 - Prob. 17.142EPCh. 17 - Prob. 17.143EPCh. 17 - Prob. 17.144EPCh. 17 - Prob. 17.145EPCh. 17 - Prob. 17.146EPCh. 17 - Prob. 17.147EPCh. 17 - Prob. 17.148EPCh. 17 - Prob. 17.149EPCh. 17 - Prob. 17.150EPCh. 17 - Prob. 17.151EPCh. 17 - Prob. 17.152EPCh. 17 - Prob. 17.153EPCh. 17 - Prob. 17.154EP
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