GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
7th Edition
ISBN: 9781305866966
Author: STOKER
Publisher: CENGAGE L
Question
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Chapter 17, Problem 17.139EP

(a)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid.  Amides are not much reactive as of carboxylic acids.  They are also stable relatively in aqueous solution.  But under strenuous conditions amides undergo hydrolysis.  The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt.  Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  1

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine.  Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid.  Amides are not much reactive as of carboxylic acids.  They are also stable relatively in aqueous solution.  But under strenuous conditions amides undergo hydrolysis.  The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt.  Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  3

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine.  Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  4

(c)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid.  Amides are not much reactive as of carboxylic acids.  They are also stable relatively in aqueous solution.  But under strenuous conditions amides undergo hydrolysis.  The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt.  Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  5

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine.  Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  6

(d)

Interpretation Introduction

Interpretation:

The structure of carbonyl-containing compound that is obtained when the given amide undergoes acidic hydrolysis has to be drawn.

Concept Introduction:

Amides are derivatives of carboxylic acid.  Amides are not much reactive as of carboxylic acids.  They are also stable relatively in aqueous solution.  But under strenuous conditions amides undergo hydrolysis.  The conditions are presence of acid, base or enzymes.

Acidic hydrolysis of amides gives the product as carboxylic acid and amine salt.  Amine salt is obtained because in acidic conditions the amine is converted into amine salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  7

Basic hydrolysis of amides gives the product as carboxylic acid salt and amine.  Carboxylic acid salt is obtained because in basic conditions the carboxylic acid is converted into carboxylic acid salt.

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP, Chapter 17, Problem 17.139EP , additional homework tip  8

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400
• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak
Could you redraw these and also explain how to solve them for me pleas

Chapter 17 Solutions

GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP

Ch. 17.4 - Prob. 1QQCh. 17.4 - Prob. 2QQCh. 17.5 - Prob. 1QQCh. 17.5 - Prob. 2QQCh. 17.5 - Prob. 3QQCh. 17.6 - Prob. 1QQCh. 17.6 - Prob. 2QQCh. 17.6 - Prob. 3QQCh. 17.7 - Prob. 1QQCh. 17.7 - Prob. 2QQCh. 17.7 - Prob. 3QQCh. 17.8 - Prob. 1QQCh. 17.8 - Prob. 2QQCh. 17.8 - Prob. 3QQCh. 17.8 - Prob. 4QQCh. 17.9 - Prob. 1QQCh. 17.9 - Prob. 2QQCh. 17.10 - Prob. 1QQCh. 17.10 - Prob. 2QQCh. 17.10 - Prob. 3QQCh. 17.10 - Prob. 4QQCh. 17.11 - Prob. 1QQCh. 17.11 - Prob. 2QQCh. 17.11 - Prob. 3QQCh. 17.12 - Prob. 1QQCh. 17.12 - Prob. 2QQCh. 17.12 - Prob. 3QQCh. 17.12 - Prob. 4QQCh. 17.13 - Prob. 1QQCh. 17.13 - Prob. 2QQCh. 17.13 - Prob. 3QQCh. 17.13 - Prob. 4QQCh. 17.14 - Prob. 1QQCh. 17.14 - Prob. 2QQCh. 17.14 - Prob. 3QQCh. 17.15 - Prob. 1QQCh. 17.15 - Prob. 2QQCh. 17.16 - Prob. 1QQCh. 17.16 - Prob. 2QQCh. 17.16 - Prob. 3QQCh. 17.17 - Prob. 1QQCh. 17.17 - Prob. 2QQCh. 17.17 - Prob. 3QQCh. 17.18 - Prob. 1QQCh. 17.18 - Prob. 2QQCh. 17.18 - Prob. 3QQCh. 17.19 - Prob. 1QQCh. 17.19 - Prob. 2QQCh. 17.19 - Prob. 3QQCh. 17.19 - Prob. 4QQCh. 17 - Prob. 17.1EPCh. 17 - Prob. 17.2EPCh. 17 - Prob. 17.3EPCh. 17 - Prob. 17.4EPCh. 17 - Prob. 17.5EPCh. 17 - Prob. 17.6EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Prob. 17.9EPCh. 17 - Prob. 17.10EPCh. 17 - Prob. 17.11EPCh. 17 - Prob. 17.12EPCh. 17 - Prob. 17.13EPCh. 17 - Prob. 17.14EPCh. 17 - Prob. 17.15EPCh. 17 - Assign a common name to each of the following...Ch. 17 - Prob. 17.17EPCh. 17 - Prob. 17.18EPCh. 17 - Prob. 17.19EPCh. 17 - Prob. 17.20EPCh. 17 - Prob. 17.21EPCh. 17 - Prob. 17.22EPCh. 17 - Prob. 17.23EPCh. 17 - Prob. 17.24EPCh. 17 - Prob. 17.25EPCh. 17 - Prob. 17.26EPCh. 17 - Prob. 17.27EPCh. 17 - Prob. 17.28EPCh. 17 - Prob. 17.29EPCh. 17 - Prob. 17.30EPCh. 17 - Prob. 17.31EPCh. 17 - Prob. 17.32EPCh. 17 - Prob. 17.33EPCh. 17 - Prob. 17.34EPCh. 17 - Determine the maximum number of hydrogen bonds...Ch. 17 - Prob. 17.36EPCh. 17 - Prob. 17.37EPCh. 17 - Prob. 17.38EPCh. 17 - Prob. 17.39EPCh. 17 - Prob. 17.40EPCh. 17 - Prob. 17.41EPCh. 17 - Prob. 17.42EPCh. 17 - Prob. 17.43EPCh. 17 - Prob. 17.44EPCh. 17 - Prob. 17.45EPCh. 17 - Prob. 17.46EPCh. 17 - Prob. 17.47EPCh. 17 - Prob. 17.48EPCh. 17 - Prob. 17.49EPCh. 17 - Prob. 17.50EPCh. 17 - Prob. 17.51EPCh. 17 - Prob. 17.52EPCh. 17 - Prob. 17.53EPCh. 17 - Prob. 17.54EPCh. 17 - Prob. 17.55EPCh. 17 - Prob. 17.56EPCh. 17 - Prob. 17.57EPCh. 17 - Prob. 17.58EPCh. 17 - Prob. 17.59EPCh. 17 - Prob. 17.60EPCh. 17 - Prob. 17.61EPCh. 17 - Prob. 17.62EPCh. 17 - Prob. 17.63EPCh. 17 - Prob. 17.64EPCh. 17 - Prob. 17.65EPCh. 17 - Prob. 17.66EPCh. 17 - Prob. 17.67EPCh. 17 - Prob. 17.68EPCh. 17 - Prob. 17.69EPCh. 17 - Prob. 17.70EPCh. 17 - Prob. 17.71EPCh. 17 - Prob. 17.72EPCh. 17 - Prob. 17.73EPCh. 17 - Prob. 17.74EPCh. 17 - Prob. 17.75EPCh. 17 - Prob. 17.76EPCh. 17 - Prob. 17.77EPCh. 17 - Prob. 17.78EPCh. 17 - Prob. 17.79EPCh. 17 - Prob. 17.80EPCh. 17 - Prob. 17.81EPCh. 17 - Prob. 17.82EPCh. 17 - Prob. 17.83EPCh. 17 - Prob. 17.84EPCh. 17 - Prob. 17.85EPCh. 17 - Prob. 17.86EPCh. 17 - Prob. 17.87EPCh. 17 - Prob. 17.88EPCh. 17 - Prob. 17.89EPCh. 17 - Prob. 17.90EPCh. 17 - Prob. 17.91EPCh. 17 - Prob. 17.92EPCh. 17 - Prob. 17.93EPCh. 17 - Prob. 17.94EPCh. 17 - Prob. 17.95EPCh. 17 - Prob. 17.96EPCh. 17 - Prob. 17.97EPCh. 17 - Prob. 17.98EPCh. 17 - Indicate whether or not each of the following...Ch. 17 - Indicate whether or not each of the following...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the following amides as...Ch. 17 - Classify each of the amides in Problem 17-101 as a...Ch. 17 - Prob. 17.104EPCh. 17 - Prob. 17.105EPCh. 17 - Prob. 17.106EPCh. 17 - Prob. 17.107EPCh. 17 - Prob. 17.108EPCh. 17 - Prob. 17.109EPCh. 17 - Prob. 17.110EPCh. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Assign an IUPAC name to each of the following...Ch. 17 - Prob. 17.113EPCh. 17 - Prob. 17.114EPCh. 17 - Prob. 17.115EPCh. 17 - Prob. 17.116EPCh. 17 - Prob. 17.117EPCh. 17 - Prob. 17.118EPCh. 17 - Prob. 17.119EPCh. 17 - What is the relationship between the acronym DEET...Ch. 17 - Prob. 17.121EPCh. 17 - Prob. 17.122EPCh. 17 - Prob. 17.123EPCh. 17 - Prob. 17.124EPCh. 17 - Prob. 17.125EPCh. 17 - Prob. 17.126EPCh. 17 - Prob. 17.127EPCh. 17 - Prob. 17.128EPCh. 17 - Prob. 17.129EPCh. 17 - Prob. 17.130EPCh. 17 - Prob. 17.131EPCh. 17 - Prob. 17.132EPCh. 17 - Prob. 17.133EPCh. 17 - Prob. 17.134EPCh. 17 - Prob. 17.135EPCh. 17 - Prob. 17.136EPCh. 17 - Prob. 17.137EPCh. 17 - Prob. 17.138EPCh. 17 - Prob. 17.139EPCh. 17 - Prob. 17.140EPCh. 17 - Prob. 17.141EPCh. 17 - Prob. 17.142EPCh. 17 - Prob. 17.143EPCh. 17 - Prob. 17.144EPCh. 17 - Prob. 17.145EPCh. 17 - Prob. 17.146EPCh. 17 - Prob. 17.147EPCh. 17 - Prob. 17.148EPCh. 17 - Prob. 17.149EPCh. 17 - Prob. 17.150EPCh. 17 - Prob. 17.151EPCh. 17 - Prob. 17.152EPCh. 17 - Prob. 17.153EPCh. 17 - Prob. 17.154EP
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