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(a)
Interpretation:
Structural formula for N,N-dimethylacetamide has to be drawn.
Concept Introduction:
Structure of the amide can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an amide the counting has to be always from the carbonyl carbon that is given the number 1.
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
(b)
Interpretation:
Structural formula for
Concept Introduction:
Structure of the amide can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an amide the counting has to be always from the carbonyl carbon that is given the number 1.
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
(c)
Interpretation:
Structural formula for 3,N-dimethylbutanamide has to be drawn.
Concept Introduction:
Structure of the amide can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an amide the counting has to be always from the carbonyl carbon that is given the number 1.
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
(d)
Interpretation:
Structural formula for formamide has to be drawn.
Concept Introduction:
Structure of the amide can be drawn from the IUPAC name. In the IUPAC name, the parent chain of carbon atom can be identified and then the substituents present in it can also be identified. With these information, the structure for the given compound can be drawn. In an amide the counting has to be always from the carbonyl carbon that is given the number 1.
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
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Chapter 17 Solutions
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
- = +92kJ ΔΗ = +170kJ Use the following reactions: 2NH3(9) N2(g) + 3H2(g) → 11/N2(g) + 2H2O (1) → NO2(g) + 2H2(g) Determine the DH° of this reaction: NO2(g) + H2(g) → 2(g) → 2H2O(l) + NH3(9) ΔΗarrow_forwardDetermine the entropy change for the reaction SO2(g) + O2(g) following information: Standard Entropy Values of Various Substance Substance SO2(g) 02(g) SO3(g) So (J/mol K) 248.2 205.0 256.8 → SO3(g) given thearrow_forwardIndicate which one of the following reactions most certainly results in a negative AS sys. O1402(g) + 3NH4NO3 (s) + C10 H22(1) → 3N2(g) + 17H2O(g) + 10CO2(g) ○ CO2(aq) = CO2(g) ○ H₂O(g) = H₂O(s) CaCO3(g) = CaO(s) + CO2(g) O CuSO4.5H2O(s) = CuSO4(s) + 5H2O(g)arrow_forward
- Estimate the DH°rxn of the reaction below: H H-C-C=C-H H Н A table of bond energy Bond H Bond Energy (kJ/mol) C-H 413 C-O 360 C=O 743 C-C 348 |C = C 612 O-H 463 H-H 436 + H-H -> H H-C. - H | | 1 HHHarrow_forwardShow work...don't give Ai generated solutionarrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 3A(g) + 1B (g) 4C (g) + 7D (g) Substance AH in kJ/mol A (g) - 25.07 B (g) - 36.51 C (g) - 90.09 D (g) + 56.11 AHran =?kJarrow_forward
- What is the change in internal energy (ΔU) when a system is heated with 42.0 J of energy while it does 110.0 J of work?arrow_forwardCan you help me solve this problem and explain what the answers are?arrow_forwardFor which reaction below does the enthalpy change under standard conditions correspond to a standard enthalpy of formation? (Choose all that applies) SO2(g) + 1/2 O2(g) → SO3(g) 2H2(g) + C(s) → CH4(g) Mg(s) + 1/2 O2(g) → MgO(s) CO(g) + H2O(g) → CO2(g) + H2(g) CO2(g) + H2(g) → CO(g) + H2O(g) 1/2 H2(g) + 1/2 N2(g) + 3/2 O2(g) → HNO3(g) CO2(g) + C(s) 2CO(g) N2(g) + 202(g) → 2NO2(g)arrow_forward
- Choose all the molecules with zero standard-enthalpy-of-formation (AH% = 0) Fe(s) FeCl2(s) N2(g) H2O(l) 02(g) C(graphite) K(s) H2O(g)arrow_forward8.5 g of potassium hydroxide (molar mass = 56.1 g/mol) dissolves in 125 g of water and the temperature of the solution increases by 15.58°C. Calculate the AH soln for potassium hydroxide. Assume the specific heat capacity of the solution is 4.2 J.g¨¹.ºC-1. KOH(s) → →K+ K(aq) + OH AH solution = ?kJ/mol (aq)arrow_forwardWhat will be the final temperature of a 8.79 g piece of iron (CP = 25.09 J/(mol · oC)) initially at 25.0oC, if it is supplied with 302.8 J from a stove?arrow_forward
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