Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1.7, Problem 1.15TIY
Interpretation Introduction

Interpretation:Themolecular orbital and energy-splitting diagram for the bonding in LiH molecule needs to be drawn.

Concept Introduction:Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals. On the basis of energy and stability these molecular orbitals can be further classified in three types:

  • Bonding molecular orbitals (BMO): They have lesser energy than atomic orbital therefore more stable compare to atomic orbital.
  • Antibonding molecular orbitals (ABMO): They have higher energy than atomic orbital therefore less stable compare to atomic orbital.
  • Non-bonding molecular orbitals (NBMO): They have same energy as atomic orbital.

Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.

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