Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1.3, Problem 1.1E

a.

Interpretation Introduction

Interpretation:The given figure needs to be redrawn for a weaker bond.

Concept introduction:A plot used to show the formation of a chemical bond in which the y-axis serves as potential energy and x-axis serves as distance separation of nuclei between two atoms is said to be potential energy diagram.

b.

Interpretation Introduction

Interpretation:The elements in the given table should be written.

Concept introduction:The smallest unit of matter that retains the chemical identity of the element is said to be an atom.

A pure substance which cannot be broken down to other smaller substances by any means that is physical or chemical is said to be an element.

A pure substance that can be separated into other smaller substances by any means that is by chemical or physical is said to be a compound.

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3. The following are some molecules:H2, HF, CO2, H2O, Cl2, NH3, CH4, CHCl3 (a)  Which of the above molecules do/does not contain polar bond? Explain your answer. (b)  Which covalent bond has the highest bond polarity among the eight molecules? (c)  (i) Which of the above molecules are non-polar molecules?                (ii) Explain why these molecules are non-polar.    4.  (d) Draw a diagram to illustrate the formation of hydrogen bonds in H2O.
A resident expert on electronegativity comes up to visit with you. He makes two claims (seen below) about electronegativity with relation to covalent bonding. Is the expert correct or can you refute him with your knowledge of electronegativity? (a) If a diatomic molecule is made up of atoms X and Y, which have different electronegativities, the molecule must be polar.     (b) The farther two atoms are apart in a bond, the larger the dipole moment will be.
Rank the bonds in each set in order of decreasing bond length and decreasing bond strength: (a) Si-F, Si-C, Si-O; (b) N=N, N-N, N=N.
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