Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1, Problem 44P
Interpretation Introduction
Interpretation:The indicated condensed formulasand Kekule structures should be drawn as bond-line formulas.
Concept introduction: There are three ways of representation of molecular structures. The hashed and wedged formulas have three types of bonds. The bond above the plane is represented by bold hash while bonds behind the plane are represented by wedge. The bonds in plane are represented by normal bonds.
Bond-line formula depicts the zig-zag framework of carbon chain with attached substituents. The terminal position represents a methyl
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 1 Solutions
Organic Chemistry: Structure and Function
Ch. 1.3 - Prob. 1.1ECh. 1.3 - Prob. 1.2ECh. 1.3 - Prob. 1.3ECh. 1.3 - Prob. 1.4ECh. 1.3 - Prob. 1.5ECh. 1.4 - Prob. 1.6ECh. 1.4 - Prob. 1.8TIYCh. 1.5 - Prob. 1.9ECh. 1.5 - Prob. 1.11TIYCh. 1.6 - Prob. 1.12E
Ch. 1.6 - Prob. 1.13ECh. 1.7 - Prob. 1.15TIYCh. 1.8 - Prob. 1.16ECh. 1.8 - Prob. 1.18TIYCh. 1.9 - Prob. 1.19ECh. 1.9 - Prob. 1.20ECh. 1.9 - Prob. 1.21ECh. 1.9 - Prob. 1.22ECh. 1 - Prob. 25PCh. 1 - Prob. 26PCh. 1 - Prob. 27PCh. 1 - Prob. 28PCh. 1 - Prob. 29PCh. 1 - Prob. 30PCh. 1 - Prob. 31PCh. 1 - Prob. 32PCh. 1 - Prob. 33PCh. 1 - Prob. 34PCh. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - Prob. 37PCh. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Prob. 44PCh. 1 - Prob. 45PCh. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - Prob. 48PCh. 1 - Prob. 49PCh. 1 - Prob. 50PCh. 1 - Prob. 51PCh. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Prob. 55PCh. 1 - Prob. 56PCh. 1 - Prob. 57PCh. 1 - Prob. 58P
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