Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1.3, Problem 1.3E
Interpretation Introduction
Interpretation: The electron-dot structures for F2, CF4, CH2Cl2, PH3, BrI, HO-, H2N- and H3C- should be drawn.
Concept introduction: Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that exist on each bonded atom.
Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons. To draw the Lewis structure, calculate the total number of valence electrons in each atom and draw the structure in such a way that each atom gets its octet configuration.
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 1 Solutions
Organic Chemistry: Structure and Function
Ch. 1.3 - Prob. 1.1ECh. 1.3 - Prob. 1.2ECh. 1.3 - Prob. 1.3ECh. 1.3 - Prob. 1.4ECh. 1.3 - Prob. 1.5ECh. 1.4 - Prob. 1.6ECh. 1.4 - Prob. 1.8TIYCh. 1.5 - Prob. 1.9ECh. 1.5 - Prob. 1.11TIYCh. 1.6 - Prob. 1.12E
Ch. 1.6 - Prob. 1.13ECh. 1.7 - Prob. 1.15TIYCh. 1.8 - Prob. 1.16ECh. 1.8 - Prob. 1.18TIYCh. 1.9 - Prob. 1.19ECh. 1.9 - Prob. 1.20ECh. 1.9 - Prob. 1.21ECh. 1.9 - Prob. 1.22ECh. 1 - Prob. 25PCh. 1 - Prob. 26PCh. 1 - Prob. 27PCh. 1 - Prob. 28PCh. 1 - Prob. 29PCh. 1 - Prob. 30PCh. 1 - Prob. 31PCh. 1 - Prob. 32PCh. 1 - Prob. 33PCh. 1 - Prob. 34PCh. 1 - Prob. 35PCh. 1 - Prob. 36PCh. 1 - Prob. 37PCh. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Prob. 44PCh. 1 - Prob. 45PCh. 1 - Prob. 46PCh. 1 - Prob. 47PCh. 1 - Prob. 48PCh. 1 - Prob. 49PCh. 1 - Prob. 50PCh. 1 - Prob. 51PCh. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Prob. 55PCh. 1 - Prob. 56PCh. 1 - Prob. 57PCh. 1 - Prob. 58P
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