Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 1, Problem 29P

(a)

Interpretation Introduction

Interpretation:The resonance structures of bicarbonate ion needs to be drawn with the use of electron pushing arrows and the form that will be the major contributor to the real structure of bicarbonate ion needs to be determined.

  Organic Chemistry: Structure and Function, Chapter 1, Problem 29P

Concept Introduction:VSEPR theory stands as Valence Shell Electron Pair Repulsion Theory. It helps to predict the molecular shape or geometry of the molecule with the help of the number of bond pair or lone pair present in it. According to VSEPR theory, the presence of lone pair on the central atom of molecule causes deviation from standard molecular geometry.

The resonance is the phenomenon in which if all the properties cannot explain by one structure, it can be shown in two or more structures by the shifting of pi bonds or lone pair but there is no change in sigma bond and position of atoms.

(b)

Interpretation Introduction

Interpretation:The resonance structures of H2CNOH needs to be drawn with the use of electron pushing arrows and the form that will be the major contributor to the real structure of H2CNOH needs to be determined.

Concept Introduction:VSEPR theory stands as Valence Shell Electron Pair Repulsion Theory. It helps to predict the molecular shape or geometry of the molecule with the help of the number of bond pair or lone pair present in it. According to VSEPR theory, the presence of lone pair on the central atom of molecule causes deviation from standard molecular geometry.

The resonance is the phenomenon in which if all the properties cannot explain by one structure, it can be shown in two or more structures by the shifting of pi bonds or lone pair but there is no change in sigma bond and position of atoms.

(c)

Interpretation Introduction

Interpretation:The resonance structures of H2CNO- needs to be drawn with the use of electron pushing arrows and the form that will be the major contributor to the real structure of H2CNOH needs to be determined.

Concept Introduction:VSEPR theory stands as Valence Shell Electron Pair Repulsion Theory. It helps to predict the molecular shape or geometry of the molecule with the help of the number of bond pair or lone pair present in it. According to VSEPR theory, the presence of lone pair on the central atom of molecule causes deviation from standard molecular geometry.

The resonance is the phenomenon in which if all the properties cannot explain by one structure, it can be shown in two or more structures by the shifting of pi bonds or lone pair but there is no change in sigma bond and position of atoms.

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Explain why only the lone pairs on the central atom are taken into consideration when predicting molecular shape
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