Concept explainers
(a)
Interpretation:The Lewis structure of Cl atom and
Concept Introduction: Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons.
The hybridization gives idea about the geometry of each atom. It can be checked with the below formula:
Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.
(b)
Interpretation:The Lewis structure of
Concept Introduction: Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons.
The hybridization gives idea about the geometry of each atom. It can be checked with the below formula:
Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.
(c)
Interpretation:The Lewis structure of
Interpretation: Interpret the Lewis structure of
Concept Introduction: Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons.
The hybridization gives idea about the geometry of each atom. It can be checked with the below formula:
Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.
(d)
Interpretation:The Lewis structure of
Concept Introduction: Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons.
The hybridization gives idea about the geometry of each atom. It can be checked with the below formula:
Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.
(e)
Interpretation:The Lewis structure of
Concept Introduction: Lewis dot structure is also known as Lewis dot formula or electron dot structure. The bond formation between the atoms takes place due to the sharing of valence electrons of bonded atoms while the remaining electrons present in outer shell represented as lone pair of electrons.
The hybridization gives idea about the geometry of each atom. It can be checked with the below formula:
Hybridization = Number of sigma bonds + Number of lone pairs on bonded atoms.
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Organic Chemistry: Structure and Function
- Describe the molecular structure around the indicated atom or atoms: (a) the sulfur atom in sulfuric acid, H2SO4[(HO)2SO2] (b) the chlorine atom in chloric acid, HClO3[HOClO2] (c) the oxygen atom in hydrogen peroxide, HNO3[HONO2] (d) the nitrogen atom in nitric acid, HNO3[HONO2] (e) the oxygen atom in the OH group in nitric acid, HNO3[HONO2] (f) the central oxygen atom in the ozone molecule, O3 (g) each of the carbon atoms in propyne, CH3CCH (h) the carbon atom in Freon, CCl2F2 (i) each of the carbon atoms in aliene, H2CCH2arrow_forwardBond Enthalpy When atoms of the hypothetical element X are placed together, they rapidly undergo reaction to form the X2 molecule: X(g)+X(g)X2(g) a Would you predict that this reaction is exothermic or endothermic? Explain. b Is the bond enthalpy of X2 a positive or a negative quantity? Why? c Suppose H for the reaction is 500 kJ/mol. Estimate the bond enthalpy of the X2 molecule. d Another hypothetical molecular compound, Y2(g), has a bond enthalpy of 750 kJ/mol, and the molecular compound XY(g) has a bond enthalpy of 1500 kJ/mol. Using bond enthalpy information, calculate H for the following reaction. X2(g)+Y2(g)2XY(g) e Given the following information, as well as the information previously presented, predict whether or not the hypothetical ionic compound AX is likely to form. In this compound, A forms the A+ cation, and X forms the X anion. Be sure to justify your answer. Reaction: A(g)+12X2(g)AX(s)The first ionization energy of A(g) is 400 kJ/mol. The electron affinity of X(g) is 525 kJ/mol. The lattice energy of AX(s) is 100 kJ/mol. f If you predicted that no ionic compound would form from the reaction in Part e, what minimum amount of AX(s) lattice energy might lead to compound formation?arrow_forwardHow does the bond energy of HCl(g) differ from the standard enthalpy of formation of HCl(g)?arrow_forward
- A common trait of simple organic compounds is to have Lewis structures where all atoms have a formal charge of zero. Consider the following incomplete Lewis structure for an organic compound called methyl cyanoacrylate, the main ingredient in Super Glue. Draw a complete Lewis structure for methyl cyanoacrylate in which all atoms have a formal charge of zero.arrow_forwardhat does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain? What is heat? Is heat the same as temperature?arrow_forward4. CHCl3 a. Lewis structure Electronic geometry_ C. d. Molecular shape_ e. Bond angle? b. Draw the different bonds and label their polarity. inorpelt b Soigns broff 02 8arrow_forward
- Draw the Lewis structure (with formal charges) of the chemical species: 1. CINO2 (N is the central atom) 2. CO3^2- 3. NO2- 4. SO3 5. BrNO2 (N is the central atom) 6. HCO3- (H is bonded to one of the O's) 7. SeO2 8. HC2O4- (each C has two O atoms and H is on one of the O's) 9. HNO3 (H is bonded to one of the O's) 10. CH3NO2 11. HCO2- (H and both O's are bonded to C)arrow_forward4. Ortho-Dichlorobenzene, C6H4Cl2, is obtained when two of the adjacent hydrogen atoms in benzene are replaced with Cl atoms. A skeleton of the molecule is shown here. a. Complete a Lewis structure for the molecule using bonds and electron pairs as needed. b. Are there any resonance structures for the molecule? If so, sketch them. c. Are the resonance structures in (a) and (b) equivalent to one another as they are in benzene? H H-C H C-Harrow_forward3. Carbon atoms will bond with each other to form a chain, often with the peripheral atoms being hydrogen. These compounds, hydrocarbons, are organic compounds composed only of carbon and hydrogen. However, when hydrogen atoms are substituted with other elements, such as fluorine, this changes the properties of the molecule. Methylfluoride (CH3F), a substituted hydrocarbon, is used in semiconductor processing. Figure 1 depicts an incorrect Lewis structure for CH3F. (QUestion shown in photo) Which reason best explains why this structure is incorrect? a) Hydrogen lacks an octet. b) Too few electrons are used. c) Carbon cannot exceed an octet. d) Fluorine atom has too many electrons.arrow_forward
- 1. Which has the smallest bond length? a. C2H6 b. C2H4 c. C2H2 d. CH4 2. Which of the following is expected to have the strongest ionic bond? a. NaF b. NaI c. CsBr d. CsFarrow_forward5. Write the chemical formula that results when the following pairs of ions combine to form an ionic bond. a. Sr2* and 02- b. Mn4 and O2- C. Lit and CI- d. Cst+ and Sz-arrow_forwardPart A Phosgene (Cl₂ CO) is a poisonous gas that was used as a chemical weapon during World War I, and it is a potential agent for chemical terrorism. Draw the Lewis structure of phosgene. Include all three resonance forms by alternating the double bond among the three terminal atoms. Draw molecules by placing atoms on the grid and connecting them with bonds. Include all nonbonding electrons. [] 22 с i H ONSAPF Br ClIX @? Morearrow_forward
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