The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows. Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

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Answer 1

Question

Chapter 16, Problem 74P

(a)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(b)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(c)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(d)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Answer 2

Question

Chapter 16, Problem 74P

(a)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(b)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(c)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(d)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

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Answer 3

Question

Chapter 16, Problem 74P

(a)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(b)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(c)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(d)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

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Answer 4

Question

Chapter 16, Problem 74P

(a)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(b)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(c)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(d)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

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Answer 5

Chapter 16, Problem 74P

(a)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(b)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(c)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

(d)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 6

Chapter 16, Problem 74P

(a)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 7

Chapter 16, Problem 74P

(a)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 8

(b)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 9

(b)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 10

(c)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 11

(c)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 12

(d)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 13

(d)

Interpretation Introduction

Interpretation: The reaction mechanism for the conversion of the starting material to final product needs to be shown using curved arrows.

Concept Introduction: In a mechanism, curved arrows are used to show the movement of electrons from one molecule to other or within a molecule. This attack always takes place from negative charge to positive thus, curved arrows are shown according to that.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 16.2 - Problem 17-1 Wrtie the IUPAC name for each...Ch. 16.2 - Prob. 16.2QC Ch. 16.2 - Prob. 16.3QC Ch. 16.4 - Prob. 16.4QC Ch. 16.4 - Prob. 16.5QC Ch. 16.4 - Problem 17-6 Show the reaction of benzaldehyde...Ch. 16.4 - Problem 17-7 Identify all hemiacetals and acetals...Ch. 16.5 - Prob. 16.8QC Ch. 16 - 17-9 Answer true or false. (a) The one aldehyde...Ch. 16 - Prob. 2P

Solution Summary: The author explains the reaction mechanism for the conversion of the starting material to final acetal product needs to be shown using curved arrows.

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