Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 16, Problem 66E

(a)

Interpretation Introduction

Interpretation:

The fraction of the tetrahedral holes occupied for Na2O should be identified.

Concept Introduction :

Closest packaging is the clear manner of arranging the atoms in the lattice. Hexagonal close packing and cubic close packing are the most commonly used closest packing. In a closest packing, ions arranged to maximize the electrostatic forces. Holes are the empty space of closest packing.

In cubic closest packing, the octahedral holes are equal to twice the number of anions present in a particular unit cell.

Also,

  Ratio of cation and anion=Number of cationNumber of anion

(b)

Interpretation Introduction

Interpretation:

The fraction of the tetrahedral holes occupied for CdS should be identified

Concept Introduction :

Closest packaging is the clear manner of arranging the atoms in the lattice. Hexagonal close packing and cubic close packing are the most commonly used closest packing. In a closest packing, ions are arranged to maximize the electrostatic forces. Holes are the empty space of closest packing.

In cubic closest packing, the octahedral holes are equal to twice the number of anions present in a particular unit cell.

Also,

  Ratio of cation and anion=Number of cationNumber of anion

(c)

Interpretation Introduction

Interpretation:

The fraction of the tetrahedral holes occupied for ZrI4 should be identified

Concept Introduction :

Closest packaging is the clear manner of arranging the atoms in the lattice. Hexagonal close packing and cubic close packing are the most commonly used closest packing. In a closest packing, ions arranged to maximize the electrostatic forces. Holes are the empty space of closest packing.

In cubic closest packing, the octahedral holes are equal to twice the number of anions present in a particular unit cell.

Also,

  Ratio of cation and anion=Number of cationNumber of anion

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Chapter 16 Solutions

Chemical Principles

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