Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 16, Problem 48E
Interpretation Introduction
Interpretation:
The metal X should be predicted.
Concept Introduction:
Unit cell is the basic unit of crystal lattice that join together to form an entire lattice of a crystal. These units are repeating units.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
a) Draw rock salt unit cell of NaCl and give the coordinates (u,v,w) describing the positions of all the atoms in such a unit
cell.
b) Calculate the structure factor |F_hkl|^ 2 for such a unit cell for x-ray scattering from a given set of crystallographic
planes (hkl).
c) Which reflection peaks have the lowest and highest intensities and why
The density of tantalum at 20oC is 16.69 g/cm3 and its unit cell is cubic. Given that the first five observed Bragg diffraction angles are θ =19.31o, 27.88o, 34.95o, 41.41o and 47.69o, find the type of unit cell and its length. Take the wavelength of the x-ray radiation to be λ =154.433 pm.
Calcium carbonate crystals in the form of aragonite have orthorhombic unit cells of dimensions a=574.1 pm , b=796,8 pm, and c=495.9 pm. Calculate the glancing angles for the {100}, {010} and {111} reflections using radiation of wavelength 83.42 pm (from aluminium)
Chapter 16 Solutions
Chemical Principles
Ch. 16 - Prob. 1DQCh. 16 - Prob. 2DQCh. 16 - Prob. 3DQCh. 16 - Prob. 4DQCh. 16 - Prob. 5DQCh. 16 - Prob. 6DQCh. 16 - Prob. 7DQCh. 16 - Prob. 8DQCh. 16 - Prob. 9DQCh. 16 - Prob. 10DQ
Ch. 16 - Prob. 11ECh. 16 - List the major types of intermolecular forces in...Ch. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Rationalize the difference in boiling points for...Ch. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Consider the following electrostatic potential...Ch. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Nickel has a face-centered cubic unit cell. The...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - The radius of tungsten is 137 pm and the density...Ch. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Describe, in general, the structures of ionic...Ch. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - Perovskite is a mineral containing calcium,...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - How does each of the following affect the rate of...Ch. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Diethyl ether (CH3CH2OCH2CH3) was one of the...Ch. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - A substance has the following properties: Sketch a...Ch. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Prob. 97ECh. 16 - Prob. 98ECh. 16 - Compare and contrast the phase diagrams of water...Ch. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - Prob. 102ECh. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Prob. 105ECh. 16 - Prob. 106ECh. 16 - The melting point of a fictional substance X is...Ch. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110AECh. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - Prob. 113AECh. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116AECh. 16 - Prob. 117AECh. 16 - Prob. 118AECh. 16 - Prob. 119AECh. 16 - Prob. 120AECh. 16 - Prob. 121AECh. 16 - Spinel is a mineral that contains 37.9%...Ch. 16 - Prob. 123AECh. 16 - Prob. 124AECh. 16 - Prob. 125AECh. 16 - Prob. 126AECh. 16 - Prob. 127AECh. 16 - Prob. 128AECh. 16 - Prob. 129AECh. 16 - Prob. 130AECh. 16 - Prob. 131AECh. 16 - Prob. 132AECh. 16 - Prob. 133AECh. 16 - Prob. 134AECh. 16 - Prob. 135AECh. 16 - Prob. 136AECh. 16 - Which of the following statements is(are) true? a....Ch. 16 - Prob. 138AECh. 16 - Prob. 139AECh. 16 - Prob. 140AECh. 16 - Prob. 141AECh. 16 - Prob. 142AECh. 16 - Prob. 143AECh. 16 - Prob. 144CPCh. 16 - Prob. 145CPCh. 16 - Prob. 146CPCh. 16 - Prob. 147CPCh. 16 - Prob. 148CPCh. 16 - Prob. 149CPCh. 16 - Prob. 150CPCh. 16 - Prob. 151CPCh. 16 - Prob. 152CPCh. 16 - Prob. 153CPCh. 16 - Prob. 154MP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is the coordination number of Cs in CsCl? of Na in NaCl? of Zn2 in ZnS?arrow_forward1. The unit cell of silicon carbide. SiC is illustrated in the margin. In what type of unit cell are the (dark gray) C atoms arranged? primitive cubic body-centered cubic face-centered cubicarrow_forward20. A unit cell has the dimensions a = 4 Å, b = 6 Å, c = 8 Å, x = ß = 90°, y = 120°. Determine: a) a*, b*, and c* for the reciprocal cell. b) The volume of the real and reciprocal unit cells. c) The spacing between the (210) planes. d) The Bragg angle 0 for reflection from the above planes.arrow_forward
- In the early days of X-ray crystallography there was an urgent need to know the wavelengths of X-rays. One technique was to measure the diffraction angle from a mechanically ruled grating. Another method was to estimate the separation of lattice planes from the measured density of a crystal. The mass density of NaCl is 2.17 g cm−3 and the (100) reflection using radiation of a certain wavelength occurred at 6.0°. Calculate the wavelength of the X-rays.arrow_forwardA3arrow_forwardThe orthorhombic unit cell of NiSO4 has the dimensions a= 634 pm, b = 784 pm, and c = 516 pm, and the density of the solid is estimated as 3.9 g cm-3. Determine the number of formula units per unit cell and calculate a moreprecise value of the density.arrow_forward
- What is the minimum number of atoms that could be containedin the unit cell of an element with a body-centeredcubic lattice? (a) 1, (b) 2, (c) 3, (d) 4, (e) 5.arrow_forwardSketch the Miller plane in a unit cell (0-1-3).arrow_forwardMake a table for comparison between the interior angles of the seven (7) unit cells and explain.There are seven types of unit cells: (1) simple cubic, (2) tetragonal, (3) orthorhombic, (4) rhombohedral, (5) monoclinic, (6) triclinic, and (7) hexagonal.arrow_forward
- 4- The unit cell of 52Cr²4 metal is BCC, if the density of Cr= 7.19 Mg/m³; determine the lattice constant of Cr unit cell?arrow_forwardA face-centred cubic (fcc) metallic crystal has four atoms per unit cell, whereas a body-centred cubic (bee) crystal has two atoms per unit cell. The separation of {100} planes of lithium metal is 350 pm and its density is 0.53 gcm-3. Is the structure of lithium fcc or bee?arrow_forwardSample Exercise 6: Empirical Formula and Density: Ionic Solid The unit cell of a binary compound of copper and oxygen is shown here. Given this image and the ionic radii rcut = 0.74 Å and ro² = 1.26 Å, (a) determine the empirical formula of this compound, (b) determine the coordination numbers of copper and oxygen, (c) estimate the length of the edge of the cubic unit cell, and (d) estimate the density of the compound. Solution (a) To determine the empirical formula we need to determine how many of each type of ion there are per unit cell. O: 8(1/8) + 1 = 2 0²-ions in the unit cell. Cu: 4(1) = 4 Cut ions in the unit cell. Empirical Formula: Cu₂O (b) If we can visually determine the coordination number of one of the ions, we can use Equation 12.1 to determine the coordination number of the other ion. Number of cations per formula unit Number of anions per formula unit anion coordination number cation coordination number Cation coordination number = anion coordination number Copper…arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Unit Cell Chemistry Simple Cubic, Body Centered Cubic, Face Centered Cubic Crystal Lattice Structu; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=HCWwRh5CXYU;License: Standard YouTube License, CC-BY