Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 16, Problem 153CP
Interpretation Introduction
Interpretation: The ionic radii for
Concept Introduction: A unit cell is defined as the smallest repeating portion in the crystal lattice.
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Chapter 16 Solutions
Chemical Principles
Ch. 16 - Prob. 1DQCh. 16 - Prob. 2DQCh. 16 - Prob. 3DQCh. 16 - Prob. 4DQCh. 16 - Prob. 5DQCh. 16 - Prob. 6DQCh. 16 - Prob. 7DQCh. 16 - Prob. 8DQCh. 16 - Prob. 9DQCh. 16 - Prob. 10DQ
Ch. 16 - Prob. 11ECh. 16 - List the major types of intermolecular forces in...Ch. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Rationalize the difference in boiling points for...Ch. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Consider the following electrostatic potential...Ch. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Nickel has a face-centered cubic unit cell. The...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - The radius of tungsten is 137 pm and the density...Ch. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Describe, in general, the structures of ionic...Ch. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - Perovskite is a mineral containing calcium,...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - How does each of the following affect the rate of...Ch. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Diethyl ether (CH3CH2OCH2CH3) was one of the...Ch. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - A substance has the following properties: Sketch a...Ch. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Prob. 97ECh. 16 - Prob. 98ECh. 16 - Compare and contrast the phase diagrams of water...Ch. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - Prob. 102ECh. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Prob. 105ECh. 16 - Prob. 106ECh. 16 - The melting point of a fictional substance X is...Ch. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110AECh. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - Prob. 113AECh. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116AECh. 16 - Prob. 117AECh. 16 - Prob. 118AECh. 16 - Prob. 119AECh. 16 - Prob. 120AECh. 16 - Prob. 121AECh. 16 - Spinel is a mineral that contains 37.9%...Ch. 16 - Prob. 123AECh. 16 - Prob. 124AECh. 16 - Prob. 125AECh. 16 - Prob. 126AECh. 16 - Prob. 127AECh. 16 - Prob. 128AECh. 16 - Prob. 129AECh. 16 - Prob. 130AECh. 16 - Prob. 131AECh. 16 - Prob. 132AECh. 16 - Prob. 133AECh. 16 - Prob. 134AECh. 16 - Prob. 135AECh. 16 - Prob. 136AECh. 16 - Which of the following statements is(are) true? a....Ch. 16 - Prob. 138AECh. 16 - Prob. 139AECh. 16 - Prob. 140AECh. 16 - Prob. 141AECh. 16 - Prob. 142AECh. 16 - Prob. 143AECh. 16 - Prob. 144CPCh. 16 - Prob. 145CPCh. 16 - Prob. 146CPCh. 16 - Prob. 147CPCh. 16 - Prob. 148CPCh. 16 - Prob. 149CPCh. 16 - Prob. 150CPCh. 16 - Prob. 151CPCh. 16 - Prob. 152CPCh. 16 - Prob. 153CPCh. 16 - Prob. 154MP
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- In the LiCl structure shown in Figure 9.21, the chloride ions form a face-centered cubic unit cell 0.513 nm on an edge. The ionic radius of Cl- is 0.181 nm. (a) Along a cell edge, how much space is between the Cl- ions? (b) Would an Na+ ion (r=0.095nm) fit into this space? a K+ ion (r=0.133nm)?arrow_forwardOutline a two-dimensional unit cell for the pattern shown here. If the black squares are labeled A and the white squares are B, what is the simplest formula for a compound based on this pattern?arrow_forwardDescribe, in general, the structures of ionic solids. Compare and contrast the structure of sodium chloride and zinc sulfide. How many tetrahedral holes and octahedral holes are there per closest packed anion? In zinc sulfide, why are only one-half of the tetrahedral holes filled with cations?arrow_forward
- Explain in words how Avogadros number could be obtained from the unit-cell edge length of a cubic crystal. What other data are required?arrow_forwardThe unit cell of silicon carbide, SiC, is illustrated below. (a) In what type of unit cell are the (dark gray) C atoms arranged? (b) If one edge of the silicon carbide unit cell is 436.0 pm, what is the calculated density of this compound? A portion of the solid-state structure of silicon carbide.arrow_forwardWhat is the coordination number of Cs in CsCl? of Na in NaCl? of Zn2 in ZnS?arrow_forward
- The free space in a metal may be found by subtracting the volume of the atoms in a unit cell from the volume of the cell. Calculate the percentage of free space in each of the three cubic lattices if all atoms in each are of equal size and touch their nearest neighbors. Which of these structures represents the most efficient packing? That is, which packs with the least amount of unused space?arrow_forwardOutline a two-dimensional unit cell for the pattern shown here. If the black squares are labeled A and the white squares are B, what is the simplest formula for a compound based on this pattern?arrow_forwardA portion of the crystalline lattice for potassium is illustrated below. (a) In what type of unit cell are the K atoms arranged? A portion of the solid-state structure of potassium. (b) If one edge of the potassium unit cell is 533 pm, what is the density of potassium?arrow_forward
- Which solid phase that is, which allotrope of carbon is more stable, graphite or diamond? You should consult some of the tables in the thermodynamics section of this text.. Both solid phases exist under normal conditions of pressure and temperature. Explain why this is so, given that one solid phase is more thermodynamically stable than the other. Do their unit cells provide any suggestion for their relative stabilities?arrow_forwardPalladium has a cubic crystal structure in which the edge of the unit cell is 389 pm long. If the density of palladium is 12.02 g/cm3, how many palladium atoms are in a unit cell? In which of the cubic unit cells does palladium crystallize?arrow_forwardAluminum metal crystallizes with a face-centered cubic unit cell. The volume of the cell is 0.0662 nm3. (a) What is the atomic radius of aluminum in cm? (b) What is the volume of a single aluminum atom? (c) What is the density of a single aluminum atom? (d) In face-centered cubic cell packing, the fraction of empty space is 26.0%. When this is factored in, what is the calculated density of aluminum?arrow_forward
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